Bridgehead enolates and bridgehead alkenes in a welwistatin model series

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Bridgehead metallation is possible in a ketone having the welwistatin skeleton, and this facilitates installation of the isothiocyanate function present in the natural product, and also enables synthesis of remarkable bridgehead alkenes.


Original languageEnglish
Pages (from-to)1398-1400
Number of pages3
JournalChemical Communications
Issue number11
Publication statusPublished - 1 Jan 2009