Beta-Chlorovinylsilanes as Masked Alkynes in Oligoyne Assembly: Synthesis of the First Aryl-End-Capped Dodecayne

Simon Simpkins; Michael Weller; Liam Cox

doi:10.1039/b707681a

Beta-Chlorovinylsilanes as Masked Alkynes in Oligoyne Assembly: Synthesis of the First Aryl-End-Capped Dodecayne

Simon Simpkins, Michael Weller, Liam Cox

Chemistry

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33 Citations (Scopus)

Abstract

An aryl-end-capped dodecayne has been prepared using a fourfold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four beta-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and 'matrix-free' MALDI-TOF mass spectrometry.

Original language	English
Pages (from-to)	4035-4037
Number of pages	3
Journal	Chemical Communications
Volume	2007
DOIs	https://doi.org/10.1039/b707681a
Publication status	Published - 1 Jan 2007

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title = "Beta-Chlorovinylsilanes as Masked Alkynes in Oligoyne Assembly: Synthesis of the First Aryl-End-Capped Dodecayne",

abstract = "An aryl-end-capped dodecayne has been prepared using a fourfold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four beta-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and 'matrix-free' MALDI-TOF mass spectrometry.",

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AU - Weller, Michael

AU - Cox, Liam

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N2 - An aryl-end-capped dodecayne has been prepared using a fourfold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four beta-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and 'matrix-free' MALDI-TOF mass spectrometry.

AB - An aryl-end-capped dodecayne has been prepared using a fourfold fluoride-mediated dechlorosilylation of a masked dodecayne precursor containing four beta-chlorovinylsilane residues that serve as masked alkynes; the unstable dodecayne product has been characterised by UV-vis absorption spectroscopy and 'matrix-free' MALDI-TOF mass spectrometry.

U2 - 10.1039/b707681a

DO - 10.1039/b707681a

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

ER -

Beta-Chlorovinylsilanes as Masked Alkynes in Oligoyne Assembly: Synthesis of the First Aryl-End-Capped Dodecayne

Abstract

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