Alkynyl sulfoxides as α-sulfinyl carbene equivalents: Gold-catalysed oxidative cyclopropanation
Research output: Contribution to journal › Article
Colleges, School and Institutes
- School of Chemistry
Alkynyl sulfoxides are shown to act as α-sulfinyl metallocarbene synthons under oxidative gold catalysis, enabling reactions that are not available from diazo-precursors. This strategy is exemplified in the synthesis of fused α-sulfinyl cyclopropanes.
|Number of pages||4|
|Early online date||4 May 2017|
|Publication status||Published - 25 May 2017|