A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts

Research output: Contribution to journalArticlepeer-review

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A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts. / Rodriguez, Paramaconi; Monzo Gimenez, Francisco Javier; Bennett, Elizabeth; Humphrey, Jo ; Plana, Daniela; Walker, Marc ; McConville, Christopher; Fermin, David .

In: ACS Catalysis, Vol. 6, No. 3, 04.03.2016, p. 1533-1539.

Research output: Contribution to journalArticlepeer-review

Harvard

Rodriguez, P, Monzo Gimenez, FJ, Bennett, E, Humphrey, J, Plana, D, Walker, M, McConville, C & Fermin, D 2016, 'A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts', ACS Catalysis, vol. 6, no. 3, pp. 1533-1539. https://doi.org/10.1021/acscatal.5b02598

APA

Rodriguez, P., Monzo Gimenez, F. J., Bennett, E., Humphrey, J., Plana, D., Walker, M., McConville, C., & Fermin, D. (2016). A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts. ACS Catalysis, 6(3), 1533-1539. https://doi.org/10.1021/acscatal.5b02598

Vancouver

Author

Rodriguez, Paramaconi ; Monzo Gimenez, Francisco Javier ; Bennett, Elizabeth ; Humphrey, Jo ; Plana, Daniela ; Walker, Marc ; McConville, Christopher ; Fermin, David . / A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts. In: ACS Catalysis. 2016 ; Vol. 6, No. 3. pp. 1533-1539.

Bibtex

@article{2ef376c6f35947fa89571d93e072f000,
title = "A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts",
abstract = "By taking advantage of the non-equilibrium synthetic conditions, the cathodic corrosion method was used to prepare a selected a number of alloys of which solid-solution alloys do not exist under ambient conditions. To illustrate our finding we present the preparation at room temperature of PtBi and PtPb alloy nanoparticles with various compositions. These alloys have shown benchmark mass activity and durability towards the formic acid oxidation. The improvement in the catalytic activity is explained based on the composition of the metal alloys, the reduced particle size and, quite importantly, the level of cleanliness of the catalyst obtained by this method.",
keywords = " alloy nanoparticles, PtBi, PtPb, formic acid oxidation, cathodic corrosion",
author = "Paramaconi Rodriguez and {Monzo Gimenez}, {Francisco Javier} and Elizabeth Bennett and Jo Humphrey and Daniela Plana and Marc Walker and Christopher McConville and David Fermin",
year = "2016",
month = mar,
day = "4",
doi = "10.1021/acscatal.5b02598",
language = "English",
volume = "6",
pages = "1533--1539",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - A synthetic route for the effective preparation of metal alloy nanoparticles and their use as active electrocatalysts

AU - Rodriguez, Paramaconi

AU - Monzo Gimenez, Francisco Javier

AU - Bennett, Elizabeth

AU - Humphrey, Jo

AU - Plana, Daniela

AU - Walker, Marc

AU - McConville, Christopher

AU - Fermin, David

PY - 2016/3/4

Y1 - 2016/3/4

N2 - By taking advantage of the non-equilibrium synthetic conditions, the cathodic corrosion method was used to prepare a selected a number of alloys of which solid-solution alloys do not exist under ambient conditions. To illustrate our finding we present the preparation at room temperature of PtBi and PtPb alloy nanoparticles with various compositions. These alloys have shown benchmark mass activity and durability towards the formic acid oxidation. The improvement in the catalytic activity is explained based on the composition of the metal alloys, the reduced particle size and, quite importantly, the level of cleanliness of the catalyst obtained by this method.

AB - By taking advantage of the non-equilibrium synthetic conditions, the cathodic corrosion method was used to prepare a selected a number of alloys of which solid-solution alloys do not exist under ambient conditions. To illustrate our finding we present the preparation at room temperature of PtBi and PtPb alloy nanoparticles with various compositions. These alloys have shown benchmark mass activity and durability towards the formic acid oxidation. The improvement in the catalytic activity is explained based on the composition of the metal alloys, the reduced particle size and, quite importantly, the level of cleanliness of the catalyst obtained by this method.

KW - alloy nanoparticles

KW - PtBi

KW - PtPb

KW - formic acid oxidation

KW - cathodic corrosion

U2 - 10.1021/acscatal.5b02598

DO - 10.1021/acscatal.5b02598

M3 - Article

VL - 6

SP - 1533

EP - 1539

JO - ACS Catalysis

JF - ACS Catalysis

SN - 2155-5435

IS - 3

ER -