Abstract
Superficially similar carbohydrate polymers from similar sources can have dramatically different characteristics. This work seeks to examine the molecular properties responsible for these differences. Protons responsible for cross-polarization in the anomeric region of Acacia nilotica (AN) were replaced easily by deuterium, but not for Acacia modesta (AM). Time constants describing the mobility and cross-polarization transfer were both found to be lower for AM. Variable contact time experiments showed poorer fits and more heterogeneity for AN. Solution state HSQC experiments showed a lower number of environments in the anomeric region for AM. The relaxation time T2 of AM solutions had a lower value consistent with a higher viscosity. The Tg′ of solutions were −14.5 °C AN and −18.5 °C AM. These results form a largely self-consistent picture of molecular differences between AN and AM, suggesting a more compact but heterogeneous structure for AN and more branching in the case of AM.
Original language | English |
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Pages (from-to) | 207-215 |
Number of pages | 9 |
Journal | Carbohydrate Polymers |
Volume | 175 |
Early online date | 24 Jul 2017 |
DOIs | |
Publication status | Published - 1 Nov 2017 |
Keywords
- Acacia modesta
- Acacia nilotica
- Arabinans
- NMR spectroscopy
- Polysaccharides
ASJC Scopus subject areas
- Organic Chemistry
- Polymers and Plastics
- Materials Chemistry