A novel protecting group methodology for syntheses using nitroxides
Research output: Contribution to journal › Article › peer-review
Colleges, School and Institutes
- Queensland University of Technology
The methoxyamine group represents an ideal protecting group for the nitroxide moiety. It can be easily and selectively introduced in high yield (typically >90%) to a range of functionalised nitroxides using FeSO 4·7H2O and H2O2 in DMSO. Its removal is readily achieved under mild conditions in high yield (70-90%) using mCPBA in a Cope-type elimination process.
|Number of pages||3|
|Publication status||Published - 14 Nov 2013|