A bright tetranuclear iridium(III) complex

Research output: Contribution to journalArticlepeer-review

Authors

  • Etienne Baranoff
  • Enrico Orselli
  • Lionel Allouche
  • Davide Di Censo
  • Rosario Scopelliti
  • Michael Grätzel
  • Md Khaja Nazeeruddin

Colleges, School and Institutes

External organisations

  • Ecole Polytechnique Federale de Lausanne
  • Swiss Federal Institute of Technology
  • Solvay Pharmaceut BV
  • IN2P3
  • Service de RMN
  • Institut de Chimie et Procédés pour l'Energie, l'Environnement et la Santé (ICPEES)

Abstract

A cyclic tetranuclear cyclometallated iridium(iii) complex using cyanide anions as bridging ligands and displaying a tetrahedrally distorted square geometry has been obtained with high yield; photo- and electrochemical characterizations show that most interesting properties of mononuclear cyclometallated iridium complexes are retained in the tetranuclear assembly.

Details

Original languageEnglish
Pages (from-to)2799-2801
Number of pages3
JournalChemical Communications
Volume47
Issue number10
Publication statusPublished - 14 Mar 2011