[2]Rotaxanes comprising a macrocylic Hamilton receptor obtained using active template synthesis: synthesis and guest complexation

Arnaud Tron; Peter J. Thornton; Brice Kauffmann; James H. R. Tucker; Nathan D. Mcclenaghan

doi:10.1080/10610278.2015.1122194

[2]Rotaxanes comprising a macrocylic Hamilton receptor obtained using active template synthesis: synthesis and guest complexation

Arnaud Tron, Peter J. Thornton, Brice Kauffmann, James H. R. Tucker, Nathan D. Mcclenaghan

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Abstract

A macrocyclic ring comprising multiple hydrogen-bonding sites as well as metal-chelating sites is shown to play the role of ligand in active templated, copper-catalysed [2]rotaxane formation via Huisgen and Glaser reactions. The crystallographic structure and copper ion binding studies are provided for the free macrocycle, along with molecular modelling, barbital, N,N′-trimethyleneurea and copper (I) binding information for the new rotaxanes

Original language	English
Pages (from-to)	733-741
Journal	Supramolecular Chemistry
Volume	28
Issue number	9-10
Early online date	11 Jan 2016
DOIs	https://doi.org/10.1080/10610278.2015.1122194
Publication status	Published - 2016

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http://www.tandfonline.com/doi/full/10.1080/10610278.2015.1122194

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title = "[2]Rotaxanes comprising a macrocylic Hamilton receptor obtained using active template synthesis: synthesis and guest complexation",

abstract = "A macrocyclic ring comprising multiple hydrogen-bonding sites as well as metal-chelating sites is shown to play the role of ligand in active templated, copper-catalysed [2]rotaxane formation via Huisgen and Glaser reactions. The crystallographic structure and copper ion binding studies are provided for the free macrocycle, along with molecular modelling, barbital, N,N′-trimethyleneurea and copper (I) binding information for the new rotaxanes",

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AU - Tron, Arnaud

AU - Thornton, Peter J.

AU - Kauffmann, Brice

AU - Tucker, James H. R.

AU - Mcclenaghan, Nathan D.

PY - 2016

Y1 - 2016

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AB - A macrocyclic ring comprising multiple hydrogen-bonding sites as well as metal-chelating sites is shown to play the role of ligand in active templated, copper-catalysed [2]rotaxane formation via Huisgen and Glaser reactions. The crystallographic structure and copper ion binding studies are provided for the free macrocycle, along with molecular modelling, barbital, N,N′-trimethyleneurea and copper (I) binding information for the new rotaxanes

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DO - 10.1080/10610278.2015.1122194

M3 - Article

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EP - 741

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

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ER -

[2]Rotaxanes comprising a macrocylic Hamilton receptor obtained using active template synthesis: synthesis and guest complexation

Abstract

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