X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

David Collison; C. David Garner; Julian Grigg; Catherine Mary McGrath; J. Frederick W Mosselmans; Elna Pidcock; Mark D. Roper; Jon M W Seddon; Ekk Sinn; Peter A. Tasker; Geoff Thornton; John F. Walsh; Nigel A. Young

X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

David Collison^*
, C. David Garner
, Julian Grigg
, Catherine Mary McGrath
, J. Frederick W Mosselmans
, Elna Pidcock
, Mark D. Roper
, Jon M W Seddon
, Ekk Sinn
, Peter A. Tasker
, Geoff Thornton
, John F. Walsh
, Nigel A. Young

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of V^V in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η²-N-O groups.

Original language	English
Pages (from-to)	2199-2204
Number of pages	6
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	13
Publication status	Published - 7 Jul 1998
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

Fingerprint

Dive into the research topics of 'X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands'. Together they form a unique fingerprint.

Cite this

Collison, D., Garner, C. D., Grigg, J., McGrath, C. M., Mosselmans, J. F. W., Pidcock, E., Roper, M. D., Seddon, J. M. W., Sinn, E., Tasker, P. A., Thornton, G., Walsh, J. F., & Young, N. A. (1998). X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands. Journal of the Chemical Society - Dalton Transactions, (13), 2199-2204.

@article{20e4b197383f44efb957ee773831bc8b,

title = "X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands",

abstract = "A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.",

author = "David Collison and Garner, \{C. David\} and Julian Grigg and McGrath, \{Catherine Mary\} and Mosselmans, \{J. Frederick W\} and Elna Pidcock and Roper, \{Mark D.\} and Seddon, \{Jon M W\} and Ekk Sinn and Tasker, \{Peter A.\} and Geoff Thornton and Walsh, \{John F.\} and Young, \{Nigel A.\}",

year = "1998",

month = jul,

day = "7",

language = "English",

pages = "2199--2204",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "13",

}

Collison, D, Garner, CD, Grigg, J, McGrath, CM, Mosselmans, JFW, Pidcock, E, Roper, MD, Seddon, JMW, Sinn, E, Tasker, PA, Thornton, G, Walsh, JF & Young, NA 1998, 'X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands', Journal of the Chemical Society - Dalton Transactions, no. 13, pp. 2199-2204.

X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands. / Collison, David; Garner, C. David; Grigg, Julian et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 13, 07.07.1998, p. 2199-2204.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

AU - Collison, David

AU - Garner, C. David

AU - Grigg, Julian

AU - McGrath, Catherine Mary

AU - Mosselmans, J. Frederick W

AU - Pidcock, Elna

AU - Roper, Mark D.

AU - Seddon, Jon M W

AU - Sinn, Ekk

AU - Tasker, Peter A.

AU - Thornton, Geoff

AU - Walsh, John F.

AU - Young, Nigel A.

PY - 1998/7/7

Y1 - 1998/7/7

N2 - A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.

AB - A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.

UR - https://www.scopus.com/pages/publications/33748510568

M3 - Article

AN - SCOPUS:33748510568

SN - 1472-7773

SP - 2199

EP - 2204

JO - Journal of the Chemical Society - Dalton Transactions

JF - Journal of the Chemical Society - Dalton Transactions

IS - 13

ER -