X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

David Collison; C. David Garner; Julian Grigg; Catherine Mary McGrath; J. Frederick W Mosselmans; Elna Pidcock; Mark D. Roper; Jon M W Seddon; Ekk Sinn; Peter A. Tasker; Geoff Thornton; John F. Walsh; Nigel A. Young

X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

David Collison^*, C. David Garner, Julian Grigg, Catherine Mary McGrath, J. Frederick W Mosselmans, Elna Pidcock, Mark D. Roper, Jon M W Seddon, Ekk Sinn, Peter A. Tasker, Geoff Thornton, John F. Walsh, Nigel A. Young

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of V^V in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η²-N-O groups.

Original language	English
Pages (from-to)	2199-2204
Number of pages	6
Journal	Journal of the Chemical Society - Dalton Transactions
Issue number	13
Publication status	Published - 7 Jul 1998
Externally published	Yes

ASJC Scopus subject areas

General Chemistry

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Collison, D., Garner, C. D., Grigg, J., McGrath, C. M., Mosselmans, J. F. W., Pidcock, E., Roper, M. D., Seddon, J. M. W., Sinn, E., Tasker, P. A., Thornton, G., Walsh, J. F., & Young, N. A. (1998). X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands. Journal of the Chemical Society - Dalton Transactions, (13), 2199-2204.

@article{20e4b197383f44efb957ee773831bc8b,

title = "X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands",

abstract = "A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.",

author = "David Collison and Garner, {C. David} and Julian Grigg and McGrath, {Catherine Mary} and Mosselmans, {J. Frederick W} and Elna Pidcock and Roper, {Mark D.} and Seddon, {Jon M W} and Ekk Sinn and Tasker, {Peter A.} and Geoff Thornton and Walsh, {John F.} and Young, {Nigel A.}",

year = "1998",

month = jul,

day = "7",

language = "English",

pages = "2199--2204",

journal = "Journal of the Chemical Society - Dalton Transactions",

issn = "1472-7773",

publisher = "Royal Society of Chemistry",

number = "13",

}

Collison, D, Garner, CD, Grigg, J, McGrath, CM, Mosselmans, JFW, Pidcock, E, Roper, MD, Seddon, JMW, Sinn, E, Tasker, PA, Thornton, G, Walsh, JF & Young, NA 1998, 'X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands', Journal of the Chemical Society - Dalton Transactions, no. 13, pp. 2199-2204.

X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands. / Collison, David; Garner, C. David; Grigg, Julian et al.
In: Journal of the Chemical Society - Dalton Transactions, No. 13, 07.07.1998, p. 2199-2204.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - X-ray absorption fine structure study of the bound state electronic transitions at the vanadium K and L edges in low symmetry, molecular, vanadium-(IV) and -(V) complexes with oxyoxime and oxyoximate ligands

AU - Collison, David

AU - Garner, C. David

AU - Grigg, Julian

AU - McGrath, Catherine Mary

AU - Mosselmans, J. Frederick W

AU - Pidcock, Elna

AU - Roper, Mark D.

AU - Seddon, Jon M W

AU - Sinn, Ekk

AU - Tasker, Peter A.

AU - Thornton, Geoff

AU - Walsh, John F.

AU - Young, Nigel A.

PY - 1998/7/7

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N2 - A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.

AB - A combination of vanadium K- and L-edge XAFS has been used to characterise a series of monomeric oxovanadium(IV), monomeric dioxovanadium(V) and dimeric oxovanadium(V) complexes with oxyoxime and oxyoximate ligands. The K- and L-edge spectra confirm the presence of VV in the dimeric species and the L-edge spectra have been used to discriminate between six-co-ordinate V-N-O-V bridged oxovanadium(V) dimers and seven-co-ordinate phenolate bridged oxovanadium(V) dimers containing η2-N-O groups.

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