Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation

Richmond Lee; Ganna Gryn'ova; K. U. Ingold; Michelle L. Coote

doi:10.1039/c6cp04670c

Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation

Richmond Lee, Ganna Gryn'ova, K. U. Ingold, Michelle L. Coote

Chemistry

Research output: Contribution to journal › Article › peer-review

Original language	English
Pages (from-to)	23673-23679
Journal	Physical Chemistry Chemical Physics
Volume	18
DOIs	https://doi.org/10.1039/c6cp04670c
Publication status	Published - 2016

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10.1039/c6cp04670c

Cite this

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title = "Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation",

author = "Richmond Lee and Ganna Gryn'ova and Ingold, {K. U.} and Coote, {Michelle L.}",

year = "2016",

doi = "10.1039/c6cp04670c",

language = "English",

volume = "18",

pages = "23673--23679",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

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Why are sec-alkylperoxyl bimolecular self-reactions orders of magnitude faster than the analogous reactions of tert-alkylperoxyls? The unanticipated role of CH hydrogen bond donation. / Lee, Richmond; Gryn'ova, Ganna; Ingold, K. U. et al.
In: Physical Chemistry Chemical Physics, Vol. 18, 2016, p. 23673-23679.

Research output: Contribution to journal › Article › peer-review

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AU - Lee, Richmond

AU - Gryn'ova, Ganna

AU - Ingold, K. U.

AU - Coote, Michelle L.

PY - 2016

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JF - Physical Chemistry Chemical Physics

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