Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa, Luis A. Román-Ramírez, Paul A. Anderson, Gary A. Leeke*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

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Abstract

Phase equilibrium data (p, T, y) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract:
Original languageEnglish
Article number86
Number of pages13
JournalInternational Journal of Thermophysics
Volume44
Issue number6
Early online date17 Apr 2023
DOIs
Publication statusPublished - Jun 2023

Keywords

  • Article
  • Electrolyte
  • Linear carbonates
  • Lithium-ion batteries
  • Peng–Robinson equation of state
  • Solubility
  • Vapor equilibrium

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