Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa; Luis A. Román-Ramírez; Paul A. Anderson; Gary A. Leeke

doi:10.1007/s10765-023-03186-2

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Shiva J. Jethwa, Luis A. Román-Ramírez, Paul A. Anderson, Gary A. Leeke^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

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Abstract

Phase equilibrium data (p, T, y) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract:

Original language	English
Article number	86
Number of pages	13
Journal	International Journal of Thermophysics
Volume	44
Issue number	6
Early online date	17 Apr 2023
DOIs	https://doi.org/10.1007/s10765-023-03186-2
Publication status	Published - Jun 2023

Keywords

Article
Electrolyte
Linear carbonates
Lithium-ion batteries
Peng–Robinson equation of state
Solubility
Vapor equilibrium

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1007/s10765-023-03186-2Licence: Creative Commons: Attribution (CC BY)

JethwaS2023Vapor.pdfFinal published version, 1.04 MBLicence: Creative Commons: Attribution (CC BY)

Recycling of Li-ion Batteries 3
Leeke, G. (Co-Investigator), Slater, P. (Co-Investigator), Kendrick, E. (Co-Investigator), Reed, D. (Co-Investigator), Allan, P. (Co-Investigator), Stolkin, R. (Co-Investigator) & Anderson, P. (Principal Investigator)
The Faraday Institution
1/04/23 → 31/03/25
Project: Research
Recycling of Li-ion Batteries 2
Allan, P. (Co-Investigator), Anderson, P. (Principal Investigator), Leeke, G. (Co-Investigator), Slater, P. (Co-Investigator), Stolkin, R. (Co-Investigator), Reed, D. (Co-Investigator), Kendrick, E. (Co-Investigator) & Lee, R. (Co-Investigator)
The Faraday Institution
1/04/21 → 31/03/23
Project: Research
ReLIB - Faraday Challenge Fast Track proposal - Circular economy
Elliott, R. (Co-Investigator), Lee, R. (Co-Investigator), Allan, P. (Co-Investigator), Slater, P. (Co-Investigator), Stolkin, R. (Co-Investigator), Walton, A. (Co-Investigator), Overton, T. (Co-Investigator), Reed, D. (Co-Investigator), Anderson, P. (Principal Investigator), Windridge, D. (Co-Investigator) & Gough, R. (Co-Investigator)
Engineering & Physical Science Research Council
1/03/18 → 30/06/21
Project: Research Councils

Cite this

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title = "Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide",

abstract = "Phase equilibrium data (p, T, y) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract:",

keywords = "Article, Electrolyte, Linear carbonates, Lithium-ion batteries, Peng–Robinson equation of state, Solubility, Vapor equilibrium",

author = "Jethwa, {Shiva J.} and Rom{\'a}n-Ram{\'i}rez, {Luis A.} and Anderson, {Paul A.} and Leeke, {Gary A.}",

year = "2023",

month = jun,

doi = "10.1007/s10765-023-03186-2",

language = "English",

volume = "44",

journal = "International Journal of Thermophysics",

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T1 - Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

AU - Jethwa, Shiva J.

AU - Román-Ramírez, Luis A.

AU - Anderson, Paul A.

AU - Leeke, Gary A.

PY - 2023/6

Y1 - 2023/6

N2 - Phase equilibrium data (p, T, y) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract:

AB - Phase equilibrium data (p, T, y) for the binary systems of carbon dioxide + dimethyl carbonate and carbon dioxide + ethyl methyl carbonate were obtained. All systems were measured for isotherms ranging from 298.2 K to 328.2 K with pressure ranging between 0.13 MPa and 10.6 MPa. A static equilibrium technique was established with samples quantified using an offline method. The results were modeled using the Peng–Robinson equation of state with van der Waals one-fluid mixing rules. Graphical Abstract:

KW - Article

KW - Electrolyte

KW - Linear carbonates

KW - Lithium-ion batteries

KW - Peng–Robinson equation of state

KW - Solubility

KW - Vapor equilibrium

U2 - 10.1007/s10765-023-03186-2

DO - 10.1007/s10765-023-03186-2

M3 - Article

SN - 0195-928X

VL - 44

JO - International Journal of Thermophysics

JF - International Journal of Thermophysics

IS - 6

M1 - 86

ER -

Vapor Equilibrium Data for the Binary Mixtures of Dimethyl Carbonate and Ethyl Methyl Carbonate in Compressed Carbon Dioxide

Abstract

Keywords

UN SDGs

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Projects

Recycling of Li-ion Batteries 3

Recycling of Li-ion Batteries 2

ReLIB - Faraday Challenge Fast Track proposal - Circular economy

Cite this