Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques

Richard Tuckett; Gary Jarvis; Kenneth Boyle; Christopher Mayhew

doi:10.1016/S0368-2048(98)00418-6

Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques

Richard Tuckett
, Gary Jarvis
, Kenneth Boyle
, Christopher Mayhew

Research output: Contribution to journal › Article › peer-review

Abstract

We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.

Original language	English
Pages (from-to)	93-99
Journal	Journal of Electron Spectroscopy and Related Phenomena
Volume	101-103
DOIs	https://doi.org/10.1016/S0368-2048(98)00418-6
Publication status	Published - 1 Jun 1999

Keywords

photofragmentation
coincidence experiments
perfluorocarbon cations

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http://www.sciencedirect.com/science/article/pii/S0368204898004186Licence: None: All rights reserved

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title = "Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques",

abstract = "We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.",

keywords = "photofragmentation , coincidence experiments , perfluorocarbon cations",

author = "Richard Tuckett and Gary Jarvis and Kenneth Boyle and Christopher Mayhew",

year = "1999",

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doi = "10.1016/S0368-2048(98)00418-6",

language = "English",

volume = "101-103",

pages = "93--99",

journal = "Journal of Electron Spectroscopy and Related Phenomena",

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TY - JOUR

T1 - Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques

AU - Tuckett, Richard

AU - Jarvis, Gary

AU - Boyle, Kenneth

AU - Mayhew, Christopher

PY - 1999/6/1

Y1 - 1999/6/1

N2 - We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.

AB - We describe an apparatus for performing three types of coincidence experiment to study state-selected photofragmentation of polyatomic ions in the gas phase; threshold photoelectron–photoion coincidences (TPEPICO), photoion–fluorescence coincidences (PIFCO), and threshold photoelectron–fluorescence coincidences (TPEFCO). Photoionisation in the vacuum-UV, 10–25 eV, is obtained using tunable radiation from the Daresbury, UK Synchrotron Radiation Source. Examples are taken from published work in CF4+, PCl3+ and PBr3+, and a range of perfluorocarbon cations CxFy+.

KW - photofragmentation

KW - coincidence experiments

KW - perfluorocarbon cations

U2 - 10.1016/S0368-2048(98)00418-6

DO - 10.1016/S0368-2048(98)00418-6

M3 - Article

SN - 0368-2048

VL - 101-103

SP - 93

EP - 99

JO - Journal of Electron Spectroscopy and Related Phenomena

JF - Journal of Electron Spectroscopy and Related Phenomena

ER -

Vacuum-UV photofragmentation of polyatomic ions using coincidence techniques

Abstract

Keywords

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