Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization

Yuki Shirosaki; Satoshi Hayakawa; Yuri Nakamura; Hiroki Yoshihara; Akiyoshi Osaka; Artemis Stamboulis

Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization

Yuki Shirosaki, Satoshi Hayakawa, Yuri Nakamura, Hiroki Yoshihara, Akiyoshi Osaka, Artemis Stamboulis

Metallurgy and Materials

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

When solution of a polymer with some inorganic ions is electrospun, the polymer fibrils will be elongated within the spinning direction and those ions are held in the inter-fibril spaces. When those electrospun fibers are calcined, ceramic fibers will be obtained. The present study has attempted to employ such spaces formed in polyvinyl alcohol) (PVA) as nano- or micro-reactor spaces for precipitation of nano-crystalline particles. Exposing the spun PVA mats to ammonia vapor fixed metal ions in the form of hydroxide and, induced apatitic calcium phosphate crystallites when the precursor solution involved calcium and hydrogen orthophosphate ions.

Original language	English
Title of host publication	Advances in Bioceramics and Porous Ceramics VII: Ceramic Engineering and Science Proceedings
Publisher	American Ceramic Society
Pages	33-38
Number of pages	6
Volume	35
Edition	5
ISBN (Print)	9781119040439
Publication status	Published - 2014
Event	Advances in Bioceramics and Porous Ceramics - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014 - Daytona Beach, United States Duration: 26 Jan 2014 → 31 Jan 2014

Conference

Conference	Advances in Bioceramics and Porous Ceramics - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014
Country/Territory	United States
City	Daytona Beach
Period	26/01/14 → 31/01/14

ASJC Scopus subject areas

Ceramics and Composites
Materials Chemistry

Cite this

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title = "Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization",

abstract = "When solution of a polymer with some inorganic ions is electrospun, the polymer fibrils will be elongated within the spinning direction and those ions are held in the inter-fibril spaces. When those electrospun fibers are calcined, ceramic fibers will be obtained. The present study has attempted to employ such spaces formed in polyvinyl alcohol) (PVA) as nano- or micro-reactor spaces for precipitation of nano-crystalline particles. Exposing the spun PVA mats to ammonia vapor fixed metal ions in the form of hydroxide and, induced apatitic calcium phosphate crystallites when the precursor solution involved calcium and hydrogen orthophosphate ions.",

author = "Yuki Shirosaki and Satoshi Hayakawa and Yuri Nakamura and Hiroki Yoshihara and Akiyoshi Osaka and Artemis Stamboulis",

year = "2014",

language = "English",

isbn = "9781119040439",

volume = "35",

pages = "33--38",

booktitle = "Advances in Bioceramics and Porous Ceramics VII: Ceramic Engineering and Science Proceedings",

publisher = "American Ceramic Society",

address = "United States",

edition = "5",

note = "Advances in Bioceramics and Porous Ceramics - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014 ; Conference date: 26-01-2014 Through 31-01-2014",

}

Shirosaki, Y, Hayakawa, S, Nakamura, Y, Yoshihara, H, Osaka, A & Stamboulis, A 2014, Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization. in Advances in Bioceramics and Porous Ceramics VII: Ceramic Engineering and Science Proceedings. 5 edn, vol. 35, American Ceramic Society, pp. 33-38, Advances in Bioceramics and Porous Ceramics - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014, Daytona Beach, United States, 26/01/14.

Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization. / Shirosaki, Yuki; Hayakawa, Satoshi; Nakamura, Yuri et al.
Advances in Bioceramics and Porous Ceramics VII: Ceramic Engineering and Science Proceedings. Vol. 35 5. ed. American Ceramic Society, 2014. p. 33-38.

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

TY - GEN

T1 - Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization

AU - Shirosaki, Yuki

AU - Hayakawa, Satoshi

AU - Nakamura, Yuri

AU - Yoshihara, Hiroki

AU - Osaka, Akiyoshi

AU - Stamboulis, Artemis

PY - 2014

Y1 - 2014

N2 - When solution of a polymer with some inorganic ions is electrospun, the polymer fibrils will be elongated within the spinning direction and those ions are held in the inter-fibril spaces. When those electrospun fibers are calcined, ceramic fibers will be obtained. The present study has attempted to employ such spaces formed in polyvinyl alcohol) (PVA) as nano- or micro-reactor spaces for precipitation of nano-crystalline particles. Exposing the spun PVA mats to ammonia vapor fixed metal ions in the form of hydroxide and, induced apatitic calcium phosphate crystallites when the precursor solution involved calcium and hydrogen orthophosphate ions.

AB - When solution of a polymer with some inorganic ions is electrospun, the polymer fibrils will be elongated within the spinning direction and those ions are held in the inter-fibril spaces. When those electrospun fibers are calcined, ceramic fibers will be obtained. The present study has attempted to employ such spaces formed in polyvinyl alcohol) (PVA) as nano- or micro-reactor spaces for precipitation of nano-crystalline particles. Exposing the spun PVA mats to ammonia vapor fixed metal ions in the form of hydroxide and, induced apatitic calcium phosphate crystallites when the precursor solution involved calcium and hydrogen orthophosphate ions.

UR - http://www.scopus.com/inward/record.url?scp=84922507748&partnerID=8YFLogxK

M3 - Conference contribution

AN - SCOPUS:84922507748

SN - 9781119040439

VL - 35

SP - 33

EP - 38

BT - Advances in Bioceramics and Porous Ceramics VII: Ceramic Engineering and Science Proceedings

PB - American Ceramic Society

T2 - Advances in Bioceramics and Porous Ceramics - 38th International Conference on Advanced Ceramics and Composites, ICACC 2014

Y2 - 26 January 2014 through 31 January 2014

ER -

Use of inter-fibril spaces among electrospun fibrils as ion-fixation and nano-crystallization

Abstract

Conference

ASJC Scopus subject areas

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Cite this