Unusual mechanistic course of some NHC-mediated transesterifications

Luca Pignataro; Teresa Papalia; Alexandra M.Z. Slawin; Stephen M. Goldup

doi:10.1021/ol900257t

Unusual mechanistic course of some NHC-mediated transesterifications

Luca Pignataro^*
, Teresa Papalia
, Alexandra M.Z. Slawin
, Stephen M. Goldup

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.

Original language	English
Pages (from-to)	1643-1646
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	7
DOIs	https://doi.org/10.1021/ol900257t
Publication status	Published - 2 Apr 2009

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/ol900257t

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@article{9f9c645218644ee3ad93e6401622d6e0,

title = "Unusual mechanistic course of some NHC-mediated transesterifications",

abstract = "During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.",

author = "Luca Pignataro and Teresa Papalia and Slawin, \{Alexandra M.Z.\} and Goldup, \{Stephen M.\}",

year = "2009",

month = apr,

day = "2",

doi = "10.1021/ol900257t",

language = "English",

volume = "11",

pages = "1643--1646",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "7",

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TY - JOUR

T1 - Unusual mechanistic course of some NHC-mediated transesterifications

AU - Pignataro, Luca

AU - Papalia, Teresa

AU - Slawin, Alexandra M.Z.

AU - Goldup, Stephen M.

PY - 2009/4/2

Y1 - 2009/4/2

N2 - During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.

AB - During experiments on the transesterification of vinyl benzoate with ethanol mediated by IPr and IMes, unexpected species were observed and characterized that call into question the accepted mechanism of the NHC-mediated transesterification of vinyl esters.

UR - https://www.scopus.com/pages/publications/64349083101

U2 - 10.1021/ol900257t

DO - 10.1021/ol900257t

M3 - Article

C2 - 19320507

AN - SCOPUS:64349083101

SN - 1523-7060

VL - 11

SP - 1643

EP - 1646

JO - Organic Letters

JF - Organic Letters

IS - 7

ER -

Unusual mechanistic course of some NHC-mediated transesterifications

Abstract

ASJC Scopus subject areas

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