Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Megan Davies; AJ Clarke; GJ Clarkson; M Shipman; James Tucker

doi:10.1039/b712447c

Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Megan Davies, AJ Clarke, GJ Clarkson, M Shipman, James Tucker

Research output: Contribution to journal › Article

16 Citations (Scopus)

Abstract

The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).

Original language	English
Pages (from-to)	5078
Number of pages	1
Journal	Chemical Communications
Volume	47
DOIs	https://doi.org/10.1039/b712447c
Publication status	Published - 1 Jan 2007

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title = "Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion",

abstract = "The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).",

author = "Megan Davies and AJ Clarke and GJ Clarkson and M Shipman and James Tucker",

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doi = "10.1039/b712447c",

language = "English",

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publisher = "Royal Society of Chemistry",

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T1 - Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

AU - Davies, Megan

AU - Clarke, AJ

AU - Clarkson, GJ

AU - Shipman, M

AU - Tucker, James

PY - 2007/1/1

Y1 - 2007/1/1

N2 - The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).

AB - The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k=40 s(-1) at 303 K).

U2 - 10.1039/b712447c

DO - 10.1039/b712447c

M3 - Article

C2 - 18049759

SN - 1364-548X

VL - 47

SP - 5078

JO - Chemical Communications

JF - Chemical Communications

ER -

Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Abstract

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