Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour

Zhilin Guo; Yi-Fei Deng; Yipei Zhang; Zoe Pikramenou; Yuan-Zhu Zhang

doi:10.1039/d0dt01461c

Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour

Zhilin Guo
, Yi-Fei Deng
, Yipei Zhang
, Zoe Pikramenou
, Yuan-Zhu Zhang

Research output: Contribution to journal › Article › peer-review

Abstract

The self-assembly of Co(ii) salts, pyridazine derivatives and azides afforded two azido-bridged [2×2] grid-type complexes {[(L)4CoII4(N3)4][BPh4]4}·sol (1, L = 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine (pzdz) and sol = 4CH3CN·3CHCl3·2CH3OH and 2, L = 3,6-di(pyridin-2-yl)pyridazine (pydz) and sol = 4CH3CN). Upon comparison with other related grid-like complexes, the incorporation of end-on azido-bridges resulted in overall intramolecular ferromagnetic couplings, and thus endowed complexes 1 and 2 single molecule magnet behaviour with field-induced slow magnetic relaxation.

Original language	English
Pages (from-to)	9218-9222
Number of pages	5
Journal	Dalton Transactions
Volume	49
Issue number	27
DOIs	https://doi.org/10.1039/d0dt01461c
Publication status	Published - 17 Jul 2020

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title = "Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour",

abstract = "The self-assembly of Co(ii) salts, pyridazine derivatives and azides afforded two azido-bridged [2×2] grid-type complexes \{[(L)4CoII4(N3)4][BPh4]4\}·sol (1, L = 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine (pzdz) and sol = 4CH3CN·3CHCl3·2CH3OH and 2, L = 3,6-di(pyridin-2-yl)pyridazine (pydz) and sol = 4CH3CN). Upon comparison with other related grid-like complexes, the incorporation of end-on azido-bridges resulted in overall intramolecular ferromagnetic couplings, and thus endowed complexes 1 and 2 single molecule magnet behaviour with field-induced slow magnetic relaxation.",

author = "Zhilin Guo and Yi-Fei Deng and Yipei Zhang and Zoe Pikramenou and Yuan-Zhu Zhang",

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doi = "10.1039/d0dt01461c",

language = "English",

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T1 - Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour

AU - Guo, Zhilin

AU - Deng, Yi-Fei

AU - Zhang, Yipei

AU - Pikramenou, Zoe

AU - Zhang, Yuan-Zhu

PY - 2020/7/17

Y1 - 2020/7/17

N2 - The self-assembly of Co(ii) salts, pyridazine derivatives and azides afforded two azido-bridged [2×2] grid-type complexes {[(L)4CoII4(N3)4][BPh4]4}·sol (1, L = 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine (pzdz) and sol = 4CH3CN·3CHCl3·2CH3OH and 2, L = 3,6-di(pyridin-2-yl)pyridazine (pydz) and sol = 4CH3CN). Upon comparison with other related grid-like complexes, the incorporation of end-on azido-bridges resulted in overall intramolecular ferromagnetic couplings, and thus endowed complexes 1 and 2 single molecule magnet behaviour with field-induced slow magnetic relaxation.

AB - The self-assembly of Co(ii) salts, pyridazine derivatives and azides afforded two azido-bridged [2×2] grid-type complexes {[(L)4CoII4(N3)4][BPh4]4}·sol (1, L = 3,6-bis(3,5-dimethyl-1H-pyrazol-1-yl)pyridazine (pzdz) and sol = 4CH3CN·3CHCl3·2CH3OH and 2, L = 3,6-di(pyridin-2-yl)pyridazine (pydz) and sol = 4CH3CN). Upon comparison with other related grid-like complexes, the incorporation of end-on azido-bridges resulted in overall intramolecular ferromagnetic couplings, and thus endowed complexes 1 and 2 single molecule magnet behaviour with field-induced slow magnetic relaxation.

U2 - 10.1039/d0dt01461c

DO - 10.1039/d0dt01461c

M3 - Article

C2 - 32573643

SN - 1477-9234

VL - 49

SP - 9218

EP - 9222

JO - Dalton Transactions

JF - Dalton Transactions

IS - 27

ER -

Two azido-bridged [2×2] cobalt(ii) grids featuring single-molecule magnet behaviour

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