Tuning coordination chemistry through the second sphere in designed metallocoiled coils

Louise N Slope; Michael G Hill; Catherine F Smith; Paul Teare; Felicity J de Cogan; Melanie M Britton; Anna F A Peacock

doi:10.1039/c9cc08189e

Tuning coordination chemistry through the second sphere in designed metallocoiled coils

Louise N Slope, Michael G Hill, Catherine F Smith, Paul Teare, Felicity J de Cogan, Melanie M Britton, Anna F A Peacock

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

180 Downloads (Pure)

Abstract

The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.

Original language	English
Pages (from-to)	3729-3732
Number of pages	4
Journal	Chemical communications (Cambridge, England)
Volume	56
Issue number	26
Early online date	26 Feb 2020
DOIs	https://doi.org/10.1039/c9cc08189e
Publication status	Published - 4 Apr 2020

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Slope_et_al_2020_Tuning_coordination_chemistry_Chemical_CommunicationsFinal published version, 1.82 MBLicence: Creative Commons: Attribution (CC BY)

https://doi.org/10.1039/C9CC08189ELicence: Creative Commons: Attribution (CC BY)

Cite this

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AU - Hill, Michael G

AU - Smith, Catherine F

AU - Teare, Paul

AU - de Cogan, Felicity J

AU - Britton, Melanie M

AU - Peacock, Anna F A

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AB - The metal hydration state within a designed coiled coil can be progressively tuned across the full integer range (3 → 0 aqua ligands), by careful choice of a second sphere terminal residue, including the lesser used Trp. Potential implications include a four-fold change in MRI relaxivity when applied to lanthanide coiled coils.

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Tuning coordination chemistry through the second sphere in designed metallocoiled coils

Abstract

ASJC Scopus subject areas

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