Abstract
Applications from nuclear energy to rockets and jet engines are underpinned by advanced high temper- ature materials. Whilst state of the art, the performance of current nickel-based superalloys is funda- mentally limited to Ni’s melting point, Tm = 1455 ◦C . Here, we develop an analogous superalloy concept but with superior high temperature capability by transitioning to a bcc tungsten base, Tm = 3422 ◦C . This strategy involves reinforcing bcc β-W by β′ TiFe intermetallic compound, which results in impressive high temperature compressive strengths of 500 MPa at 1000 ◦C . This bcc-superalloy design approach has wider applicability to other bcc alloy bases, including Mo, Ta, and Nb, as well as to refractory-metal high entropy alloys (RHEAs). By investigation of the underlying phase equilibria, thermodynamic modelling, characterisation and mechanical properties, we demonstrate the capability of ternary W-Ti-Fe tungsten- based bcc-superalloys as a new class of high temperature materials.
Original language | English |
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Article number | 101014 |
Journal | Applied Materials Today |
Volume | 23 |
Early online date | 30 Mar 2021 |
DOIs | |
Publication status | Published - Jun 2021 |
Keywords
- High temperature materials
- Intermetallics
- Phase equilibria
- Precipitation
- Tungsten
ASJC Scopus subject areas
- General Materials Science