Abstract
Monitoring of mechanochemical thiocarbamoylation by in situ Raman spectroscopy revealed the formation of aryl N-thiocarbamoylbenzotriazoles, reactive intermediates deemed unisolable in solution. The first-time isolation and structural characterization of these elusive molecules demonstrates the ability of mechanochemistry to access otherwise unobtainable intermediates and offers a new range of masked isothiocyanate reagents.
| Original language | English |
|---|---|
| Pages (from-to) | 8440-8443 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 54 |
| Issue number | 29 |
| DOIs | |
| Publication status | Published - 13 Jul 2015 |
Bibliographical note
Publisher Copyright:© 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
- mechanochemistry
- reactive intermediates
- thiocarbamoylation
- thiourea
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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