Transformation from rod-like to diamond-like micelles by thermally induced nucleation self-assembly

Heng Li; Liang Han; Yulin Zhu; Paco Fernández-Trillo; Feng He

doi:10.1021/acs.macromol.1c00744

Transformation from rod-like to diamond-like micelles by thermally induced nucleation self-assembly

Heng Li, Liang Han, Yulin Zhu, Paco Fernández-Trillo, Feng He

Chemistry

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Abstract

Precisely controlled organic one-dimensional (1D) and two-dimensional (2D) materials with unique optoelectronic properties have attracted wide interests. By the introduction of chlorine into the poly(p-phenylenevinylene) (PPV) core, we produced a series of 1D rod-like micelles, whose sizes were controlled by the concentrations of solutions, using self-assembly (SA) of conjugated copolymers (PPV-Cl_20%)₁₀-b-P2VP₂₀. The transformation from 1D rod-like micelles to 2D uniform diamond-like micelles was achieved by the thermally induced nucleation SA. The sizes of the 2D diamond-like micelles could be tuned by the annealing temperature and the ratio of unimer to seed. It is demonstrated that the morphology transformation from rod-like micelles to diamond-like micelles was based on energetics including thermodynamic and kinetic points.

Original language	English
Pages (from-to)	5278-5285
Number of pages	8
Journal	Macromolecules
Volume	54
Issue number	11
Early online date	24 May 2021
DOIs	https://doi.org/10.1021/acs.macromol.1c00744
Publication status	Published - 8 Jun 2021

Bibliographical note

Funding Information:
This work was supported financially by the National Natural Science Foundation of China (21975115, 21733005, and 51773087), the Shenzhen Fundamental Research Programs (JCYJ20190809161413310, JCYJ20180302180238419, and KQJSCX20180319114442157), Guangdong Provincial Key Laboratory of Catalysis (no. 2020B121201002), Guangdong Basic and Applied Basic Research Foundation (2020A1515110845), Guangdong Innovative and Entrepreneurial Research Team Program (2016ZT06G587), and Shenzhen Sci-Tech Fund (KYTDPT20181011104007). We thank the SUSTech Core Research Facilities for the AFM and TEM measurements.

Publisher Copyright:
© 2021 American Chemical Society

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/acs.macromol.1c00744

HengLi2021Transformation
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Macromolecules, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see: https://doi.org/10.1021/acs.macromol.1c00744
Accepted author manuscript, 4.32 MBLicence: None: All rights reserved

Cite this

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title = "Transformation from rod-like to diamond-like micelles by thermally induced nucleation self-assembly",

abstract = "Precisely controlled organic one-dimensional (1D) and two-dimensional (2D) materials with unique optoelectronic properties have attracted wide interests. By the introduction of chlorine into the poly(p-phenylenevinylene) (PPV) core, we produced a series of 1D rod-like micelles, whose sizes were controlled by the concentrations of solutions, using self-assembly (SA) of conjugated copolymers (PPV-Cl20%)10-b-P2VP20. The transformation from 1D rod-like micelles to 2D uniform diamond-like micelles was achieved by the thermally induced nucleation SA. The sizes of the 2D diamond-like micelles could be tuned by the annealing temperature and the ratio of unimer to seed. It is demonstrated that the morphology transformation from rod-like micelles to diamond-like micelles was based on energetics including thermodynamic and kinetic points.",

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Transformation from rod-like to diamond-like micelles by thermally induced nucleation self-assembly

Abstract

Bibliographical note

ASJC Scopus subject areas

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