trans-[Mo(CO)4{P(OMe)3}2]

Neil R. Champness; Alison M. Hopkins; Gillian Reid

doi:10.1107/S010827019501479X

trans-[Mo(CO)₄{P(OMe)₃}₂]

Neil R. Champness, Alison M. Hopkins, Gillian Reid^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Crystals of trans-tetracarbonylbis(trimethyl phosphite)-molybdenum(0) contain discrete [Mo(C₃H₉O₃P)₂(CO)₄] molecules whose metal atoms occupy crystallographic inversion centres. Valency angles at the Mo atom deviate from ideal octahedral values by no more than 3.3 (1)°. Mo-ligand bond lengths are normal, with an Mo-P distance of 2.4256 (8) and Mo-C distances of 2.041 (3) and 2.037 (4) Å.

Original language	English
Pages (from-to)	797-799
Number of pages	3
Journal	Acta Crystallographica Section C: Crystal Structure Communications
Volume	52
Issue number	4
DOIs	https://doi.org/10.1107/S010827019501479X
Publication status	Published - 15 Apr 1996

ASJC Scopus subject areas

General Biochemistry,Genetics and Molecular Biology

Access to Document

10.1107/S010827019501479X

Cite this

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title = "trans-[Mo(CO)4{P(OMe)3}2]",

abstract = "Crystals of trans-tetracarbonylbis(trimethyl phosphite)-molybdenum(0) contain discrete [Mo(C3H9O3P)2(CO)4] molecules whose metal atoms occupy crystallographic inversion centres. Valency angles at the Mo atom deviate from ideal octahedral values by no more than 3.3 (1)°. Mo-ligand bond lengths are normal, with an Mo-P distance of 2.4256 (8) and Mo-C distances of 2.041 (3) and 2.037 (4) {\AA}.",

author = "Champness, {Neil R.} and Hopkins, {Alison M.} and Gillian Reid",

year = "1996",

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language = "English",

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publisher = "International Union of Crystallography",

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T1 - trans-[Mo(CO)4{P(OMe)3}2]

AU - Champness, Neil R.

AU - Hopkins, Alison M.

AU - Reid, Gillian

PY - 1996/4/15

Y1 - 1996/4/15

N2 - Crystals of trans-tetracarbonylbis(trimethyl phosphite)-molybdenum(0) contain discrete [Mo(C3H9O3P)2(CO)4] molecules whose metal atoms occupy crystallographic inversion centres. Valency angles at the Mo atom deviate from ideal octahedral values by no more than 3.3 (1)°. Mo-ligand bond lengths are normal, with an Mo-P distance of 2.4256 (8) and Mo-C distances of 2.041 (3) and 2.037 (4) Å.

AB - Crystals of trans-tetracarbonylbis(trimethyl phosphite)-molybdenum(0) contain discrete [Mo(C3H9O3P)2(CO)4] molecules whose metal atoms occupy crystallographic inversion centres. Valency angles at the Mo atom deviate from ideal octahedral values by no more than 3.3 (1)°. Mo-ligand bond lengths are normal, with an Mo-P distance of 2.4256 (8) and Mo-C distances of 2.041 (3) and 2.037 (4) Å.

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DO - 10.1107/S010827019501479X

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JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

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