TY - JOUR
T1 - The relative contributions of silicate and carbonate rocks to rieverine Sr fluxes in the headwaters of the Ganges
AU - Bickle, MJ
AU - Chapman, HJ
AU - Bunbury, J
AU - Harris, NBW
AU - Fairchild, Ian
AU - Ahmad, T
AU - Pomies, C
PY - 2005/5/1
Y1 - 2005/5/1
N2 - Exhumation of the Himalayan-Tibetan orogen is implicated in the marked rise in seawater Sr-87/(86) Sr ratios since 40 Ma. However both silicate and carbonate rocks in the Himalaya have elevated Sr-87/Sr-86 ratios and there is disagreement as to how much of the Sr-87 flux is derived from silicate weathering. Most previous studies have used element ratios from bedrock to constrain the proportions of silicate- and carbonate-derived Sr in river waters. Here we use arrays of water compositions sampled from the head waters of the Ganges in the Indian and Nepalese Himalaya to constrain the end-member element ratios. The compositions of tributaries draining catchments restricted to a limited range of geological units can be described by two-component mixing of silicate and carbonate-derived components and lie on a plane in multicomponent composition space. Key elemental ratios of the carbonate and silicate components are determined by the intersection of the tributary mixing plane with the planes Na = 0 for carbonate and constant Ca/Na for silicate. The fractions of Sr derived from silicate and carbonate sources are then calculated by mass-balance in Sr-Ca-Mg-Na composition space. Comparison of end-member compositions with bedrock implies that secondary calcite deposition may be important in some catchments and that dissolution of low-Mg trace calcite in silicate rocks may explain discrepancies in Sr-Ca-Na-Mg covariation. Alternatively, composition-dependent precipitation or incongruent dissolution reactions may rotate mixing trends on cation-ratio diagrams. However the calculations are not sensitive to transformations of the compositions by incongruent dissolution or precipitation processes provided that the transformed silicate and carbonate component vectors are constrained. Silicates are calculated to provide similar to 50% of the dissolved Sr flux from the head waters of the Ganges assuming that discrepancies between Ca-Mg-Na covariation and the silicate rock compositions arise from addition of trace calcite. If the Ca-Mg-Na mixing plane is rotated by composition-dependent secondary calcite deposition, this estimate would be increased. Moreover, when Sr-87/(86) Sr ratios of the Sr inputs are considered, silicate Sr is responsible for 70 +/- 16% (1 sigma) of the Sr-87 flux forcing changes in seawater Sr-isotopic composition. Since earlier studies predict that silicate weathering generates as little as 20% of the total Sr flux in Himalayan river systems, this study demonstrates that the significance of silicate weathering can be greatly underestimated if the processes that decouple the water cation ratios from those of the source rocks are not properly evaluated. Copyright (c) 2005 Elsevier Ltd.
AB - Exhumation of the Himalayan-Tibetan orogen is implicated in the marked rise in seawater Sr-87/(86) Sr ratios since 40 Ma. However both silicate and carbonate rocks in the Himalaya have elevated Sr-87/Sr-86 ratios and there is disagreement as to how much of the Sr-87 flux is derived from silicate weathering. Most previous studies have used element ratios from bedrock to constrain the proportions of silicate- and carbonate-derived Sr in river waters. Here we use arrays of water compositions sampled from the head waters of the Ganges in the Indian and Nepalese Himalaya to constrain the end-member element ratios. The compositions of tributaries draining catchments restricted to a limited range of geological units can be described by two-component mixing of silicate and carbonate-derived components and lie on a plane in multicomponent composition space. Key elemental ratios of the carbonate and silicate components are determined by the intersection of the tributary mixing plane with the planes Na = 0 for carbonate and constant Ca/Na for silicate. The fractions of Sr derived from silicate and carbonate sources are then calculated by mass-balance in Sr-Ca-Mg-Na composition space. Comparison of end-member compositions with bedrock implies that secondary calcite deposition may be important in some catchments and that dissolution of low-Mg trace calcite in silicate rocks may explain discrepancies in Sr-Ca-Na-Mg covariation. Alternatively, composition-dependent precipitation or incongruent dissolution reactions may rotate mixing trends on cation-ratio diagrams. However the calculations are not sensitive to transformations of the compositions by incongruent dissolution or precipitation processes provided that the transformed silicate and carbonate component vectors are constrained. Silicates are calculated to provide similar to 50% of the dissolved Sr flux from the head waters of the Ganges assuming that discrepancies between Ca-Mg-Na covariation and the silicate rock compositions arise from addition of trace calcite. If the Ca-Mg-Na mixing plane is rotated by composition-dependent secondary calcite deposition, this estimate would be increased. Moreover, when Sr-87/(86) Sr ratios of the Sr inputs are considered, silicate Sr is responsible for 70 +/- 16% (1 sigma) of the Sr-87 flux forcing changes in seawater Sr-isotopic composition. Since earlier studies predict that silicate weathering generates as little as 20% of the total Sr flux in Himalayan river systems, this study demonstrates that the significance of silicate weathering can be greatly underestimated if the processes that decouple the water cation ratios from those of the source rocks are not properly evaluated. Copyright (c) 2005 Elsevier Ltd.
UR - http://www.scopus.com/inward/record.url?scp=17844379019&partnerID=8YFLogxK
U2 - 10.1016/j.gca.2004.11.019
DO - 10.1016/j.gca.2004.11.019
M3 - Article
VL - 69
SP - 2221
EP - 2240
JO - Geochimica et Cosmochimica Acta
JF - Geochimica et Cosmochimica Acta
ER -