The first Spirobifluorenes containing two Binaphthyl Moieties

Alexander Russell; Neil Spencer; D Philp; Benson Kariuki; John Snaith

doi:10.1021/om030422s

The first Spirobifluorenes containing two Binaphthyl Moieties

Alexander Russell
, Neil Spencer
, D Philp
, Benson Kariuki
, John Snaith

Chemistry

Research output: Contribution to journal › Article

14 Citations (Scopus)

Abstract

The first spirobifluorenes comprising two binaphthyl moieties with silicon or germanium at the site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both molecules have highly distorted structures, resulting in a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature dependency of the NMR spectra.

Original language	English
Pages (from-to)	5589-5592
Number of pages	4
Journal	Organometallics
Volume	22
Issue number	26
DOIs	https://doi.org/10.1021/om030422s
Publication status	Published - 22 Dec 2003

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10.1021/om030422s

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title = "The first Spirobifluorenes containing two Binaphthyl Moieties",

abstract = "The first spirobifluorenes comprising two binaphthyl moieties with silicon or germanium at the site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both molecules have highly distorted structures, resulting in a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature dependency of the NMR spectra.",

author = "Alexander Russell and Neil Spencer and D Philp and Benson Kariuki and John Snaith",

year = "2003",

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AU - Spencer, Neil

AU - Philp, D

AU - Kariuki, Benson

AU - Snaith, John

PY - 2003/12/22

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N2 - The first spirobifluorenes comprising two binaphthyl moieties with silicon or germanium at the site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both molecules have highly distorted structures, resulting in a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature dependency of the NMR spectra.

AB - The first spirobifluorenes comprising two binaphthyl moieties with silicon or germanium at the site of fusion have been synthesized and fully characterized. X-ray crystallographic analysis reveals that both molecules have highly distorted structures, resulting in a low barrier for interconversion between the two atropisomers; the barrier was calculated from the temperature dependency of the NMR spectra.

UR - https://www.scopus.com/pages/publications/0348170981

U2 - 10.1021/om030422s

DO - 10.1021/om030422s

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JO - Organometallics

JF - Organometallics

IS - 26

ER -

The first Spirobifluorenes containing two Binaphthyl Moieties

Abstract

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