The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry

Y.-G. Zhou; N.V. Rees; R.G. Compton; B. Haddou

doi:10.1039/c2cp42940c

The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry

Y.-G. Zhou
, N.V. Rees
, R.G. Compton
, B. Haddou

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

44 Citations (Scopus)

Abstract

The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ("reversible") one-electron oxidation, whilst the NiNPs exhibit slow ("irreversible") 2-electron kinetics. Kinetic parameters are reported.

Original language	English
Pages (from-to)	14354-14357
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	14
Issue number	41
Early online date	10 Sept 2012
DOIs	https://doi.org/10.1039/c2cp42940c
Publication status	Published - 7 Nov 2012

Access to Document

10.1039/c2cp42940c

Cite this

@article{f3833686af5245eda08db66b8c73a0b0,

title = "The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry",

abstract = "The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ({"}reversible{"}) one-electron oxidation, whilst the NiNPs exhibit slow ({"}irreversible{"}) 2-electron kinetics. Kinetic parameters are reported.",

author = "Y.-G. Zhou and N.V. Rees and R.G. Compton and B. Haddou",

year = "2012",

month = nov,

day = "7",

doi = "10.1039/c2cp42940c",

language = "English",

volume = "14",

pages = "14354--14357",

journal = "Physical Chemistry Chemical Physics",

issn = "1463-9076",

publisher = "Royal Society of Chemistry",

number = "41",

}

TY - JOUR

T1 - The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry

AU - Zhou, Y.-G.

AU - Rees, N.V.

AU - Compton, R.G.

AU - Haddou, B.

PY - 2012/11/7

Y1 - 2012/11/7

N2 - The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ("reversible") one-electron oxidation, whilst the NiNPs exhibit slow ("irreversible") 2-electron kinetics. Kinetic parameters are reported.

AB - The electro-oxidation of silver and nickel nanoparticles in aqueous solution was studied via their collisions with a carbon electrode. The average charge passed per impact varies with electrode potential and was analysed to determine that AgNPs display an electrochemically fast ("reversible") one-electron oxidation, whilst the NiNPs exhibit slow ("irreversible") 2-electron kinetics. Kinetic parameters are reported.

UR - https://www.scopus.com/pages/publications/84867497746

U2 - 10.1039/c2cp42940c

DO - 10.1039/c2cp42940c

M3 - Article

AN - SCOPUS:84867497746

SN - 1463-9076

VL - 14

SP - 14354

EP - 14357

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 41

ER -

The charge transfer kinetics of the oxidation of silver and nickel nanoparticles via particle-electrode impact electrochemistry

Abstract

Access to Document

Fingerprint

Cite this