Abstract
The A 2Πu-X 2Πg electronic emission spectrum of I2+ has been recorded at a low rotational temperature in a crossed molecular beam/electron beam apparatus. Six vibrational sequences with five or more members have been assigned to progressions in ν′, giving ω′e = 122±8 cm−1, but a full vibrational analysis has not been possible. It is not known whether this is due to the relatively poor resolution (≈5 cm−1) at which the spectrum has been recorded or because the A 2Πu state is perturbed in one or both spin-orbit components. Existing data on the A state of I2+ are reviewed.
Original language | English |
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Pages (from-to) | 575-580 |
Journal | Chemical Physics Letters |
Volume | 160 |
Issue number | 5-6 |
DOIs | |
Publication status | Published - 1 Aug 1989 |