Synthesis of an Achiral Isomer of Lipoic Acid As an Anchor Group for SAM Formation on Gold Surfaces

KM Joly; Giorgio Mirri; Y Willener; Sarah Horswell; CJ Moody; James Tucker

doi:10.1021/jo9024545

Synthesis of an Achiral Isomer of Lipoic Acid As an Anchor Group for SAM Formation on Gold Surfaces

KM Joly, Giorgio Mirri, Y Willener, Sarah Horswell, CJ Moody, James Tucker

Chemistry

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4 Citations (Scopus)

Abstract

Isolipoic acid, a symmetrical and achiral isomer of the commonly-used alpha-lipoic acid, has previously been overlooked as a tether group for the formation of self-assembled monolayers (SAMs). Here its ready synthesis through a new route and its functionalization with ferrocenyl groups for redox-active SAM formation on gold electrodes are described.

Original language	English
Pages (from-to)	2395-2398
Number of pages	4
Journal	The Journal of Organic Chemistry
Volume	75
Issue number	7
DOIs	https://doi.org/10.1021/jo9024545
Publication status	Published - 1 Apr 2010

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10.1021/jo9024545

Ferrocene-Based Enantioselective Sensors for Chiral Carboxylates
Tucker, J.
Engineering & Physical Science Research Council
1/10/05 → 30/06/09
Project: Research Councils

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title = "Synthesis of an Achiral Isomer of Lipoic Acid As an Anchor Group for SAM Formation on Gold Surfaces",

abstract = "Isolipoic acid, a symmetrical and achiral isomer of the commonly-used alpha-lipoic acid, has previously been overlooked as a tether group for the formation of self-assembled monolayers (SAMs). Here its ready synthesis through a new route and its functionalization with ferrocenyl groups for redox-active SAM formation on gold electrodes are described.",

author = "KM Joly and Giorgio Mirri and Y Willener and Sarah Horswell and CJ Moody and James Tucker",

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AU - Joly, KM

AU - Mirri, Giorgio

AU - Willener, Y

AU - Horswell, Sarah

AU - Moody, CJ

AU - Tucker, James

PY - 2010/4/1

Y1 - 2010/4/1

N2 - Isolipoic acid, a symmetrical and achiral isomer of the commonly-used alpha-lipoic acid, has previously been overlooked as a tether group for the formation of self-assembled monolayers (SAMs). Here its ready synthesis through a new route and its functionalization with ferrocenyl groups for redox-active SAM formation on gold electrodes are described.

AB - Isolipoic acid, a symmetrical and achiral isomer of the commonly-used alpha-lipoic acid, has previously been overlooked as a tether group for the formation of self-assembled monolayers (SAMs). Here its ready synthesis through a new route and its functionalization with ferrocenyl groups for redox-active SAM formation on gold electrodes are described.

U2 - 10.1021/jo9024545

DO - 10.1021/jo9024545

M3 - Article

C2 - 20210295

SN - 0022-3263

VL - 75

SP - 2395

EP - 2398

JO - The Journal of Organic Chemistry

JF - The Journal of Organic Chemistry

IS - 7

ER -

Synthesis of an Achiral Isomer of Lipoic Acid As an Anchor Group for SAM Formation on Gold Surfaces

Abstract

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Ferrocene-Based Enantioselective Sensors for Chiral Carboxylates

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