Synthesis and characterization of an extremely versatile structural motif called the “plum-pudding” gel

Iseult Lynch, Kenneth A. Dawson

Research output: Contribution to journalArticlepeer-review

36 Citations (Scopus)

Abstract

The “plum-pudding” gel is a composite gel structure composed of responsive microgel particles randomly dispersed in a bulk gel medium. Microgel particles can be responsive to a variety of stimuli (temperature, pH, light, etc.), and the bulk gel can be any cross-linkable material. Thus an infinite variety of materials of different mechanical and responsive properties can be envisioned based on this simple structural motif. The novelty of the plum-pudding gel is that it separates the concepts of functionality and mechanical strength. The “plum-pudding” nature of the gel was confirmed by laser scanning confocal microscopy:  the fluorescently labeled PNIPAM microgel particles resembled plums in a pudding. A model for the structure was proposed, where the growing network chains grew through the pores of the swollen microgel particles and were unaffected by their presence, resulting in an unchanged network structure at the concentrations of microgel particles studied (up to 20 mol % of the monomer content). Two examples of the diversity of the plum-pudding gel as a structural motif are illustrated. PNIPAM microgel particles are used in the first example to enhance the positive thermoresponsiveness of responsive bulk materials (NIPA-co-BAM-co-DAM gels) and in the second example to induce positive thermoresponsiveness into nonresponsive bulk gels (DAM gels).
Original languageEnglish
Pages (from-to)9629-9637
Number of pages7
JournalThe Journal of Physical Chemistry Part B: Condensed Matter, Materials, Surfaces, Interfaces & Biophysical
Volume107
Issue number36
Early online date12 Aug 2003
DOIs
Publication statusPublished - 1 Sep 2003

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