Study of boron-nitrogen dative bonds using azetidine inversion dynamics.

Cam Thuy Hoang; Ivan Prokes; Guy J Clarkson; Matthew J Rowland; James H R Tucker; Michael Shipman; Tiffany R Walsh

doi:10.1039/c3cc36159d

Study of boron-nitrogen dative bonds using azetidine inversion dynamics.

Cam Thuy Hoang
, Ivan Prokes
, Guy J Clarkson
, Matthew J Rowland
, James H R Tucker
, Michael Shipman
, Tiffany R Walsh

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by (11)B NMR, X-ray crystallography and MP2 calculations.

Original language	English
Pages (from-to)	2509-11
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	25
DOIs	https://doi.org/10.1039/c3cc36159d
Publication status	Published - 28 Mar 2013

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10.1039/c3cc36159d

Controlling the Molecular Motion Associated with Pyramidal Inversion : Towards New Types of Nanoscale Switches
Tucker, J. (Principal Investigator)
Engineering & Physical Science Research Council
1/04/08 → 31/12/10
Project: Research Councils

Cite this

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title = "Study of boron-nitrogen dative bonds using azetidine inversion dynamics.",

abstract = "A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by (11)B NMR, X-ray crystallography and MP2 calculations.",

author = "Hoang, \{Cam Thuy\} and Ivan Prokes and Clarkson, \{Guy J\} and Rowland, \{Matthew J\} and Tucker, \{James H R\} and Michael Shipman and Walsh, \{Tiffany R\}",

year = "2013",

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doi = "10.1039/c3cc36159d",

language = "English",

volume = "49",

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journal = "Chemical Communications ",

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publisher = "Royal Society of Chemistry",

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AU - Hoang, Cam Thuy

AU - Prokes, Ivan

AU - Clarkson, Guy J

AU - Rowland, Matthew J

AU - Tucker, James H R

AU - Shipman, Michael

AU - Walsh, Tiffany R

PY - 2013/3/28

Y1 - 2013/3/28

N2 - A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by (11)B NMR, X-ray crystallography and MP2 calculations.

AB - A method for probing the strength of B-N dative bonds is reported. The activation parameters for nitrogen inversion in a series of azetidines tethered to boronate esters have been quantified by VT-NMR and the measured barriers correlated with data obtained by (11)B NMR, X-ray crystallography and MP2 calculations.

U2 - 10.1039/c3cc36159d

DO - 10.1039/c3cc36159d

M3 - Article

C2 - 23423181

SN - 1359-7345

VL - 49

SP - 2509

EP - 2511

JO - Chemical Communications

JF - Chemical Communications

IS - 25

ER -

Study of boron-nitrogen dative bonds using azetidine inversion dynamics.

Abstract

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Projects

Controlling the Molecular Motion Associated with Pyramidal Inversion : Towards New Types of Nanoscale Switches

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