Stabilising and characterising homogeneous catalysts in MOFs

Sarah L. Griffin, Georgia R.F. Orton, Rosemary J. Young, Christopher J. Sumby, Christian J. Doonan, Neil R. Champness*

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingChapter

Abstract

Metal-organic frameworks (MOFs) provide a crystalline scaffold that can act as a host for guest species. In this chapter, recent advances using MOFs as hosts for catalytic metal complexes are discussed. Particular emphasis is given to MOFs that can tether metal complexes to the framework such that the guests adopt a crystalline arrangement. The structures of the tethered complexes and their reactivity can be studied by a variety of techniques, including X-ray diffraction. We discuss examples of reactive species which are kinetically trapped and structurally characterised within an MOF and reports where tethering catalysts to MOFs can lead to enhanced catalytic performance. Finally, we describe guidelines for developing such approaches and for the use of MOFs to study catalytic processes.

Original languageEnglish
Title of host publicationReactivity in Confined Spaces
EditorsRoss S. Forgan, Gareth O. Lloyd
PublisherRoyal Society of Chemistry
Chapter11
Pages340-369
Number of pages30
ISBN (Electronic)9781788019705, 9781788019712
ISBN (Print)9781788017763
DOIs
Publication statusPublished - 25 Aug 2021

Publication series

NameMonographs in Supramolecular Chemistry
Number31
Volume2021-January
ISSN (Print)1368-8642
ISSN (Electronic)2041-7144

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2021.

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

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