SQUID magnetometry as a tool for following a clock reaction in solution

R Evans; KB Henbest; MA Hayward; Melanie Britton; K Maeda; CR Timmel

doi:10.1039/b819977a

SQUID magnetometry as a tool for following a clock reaction in solution

R Evans, KB Henbest, MA Hayward, Melanie Britton, K Maeda, CR Timmel

Chemistry

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4 Citations (Scopus)

Abstract

SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(II) EDTA](2-) by H2O2, in real time and it was shown that, in combination with other methods (e. g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.

Original language	English
Pages (from-to)	2467-2469
Number of pages	3
Journal	Dalton Transactions
Issue number	14
DOIs	https://doi.org/10.1039/b819977a
Publication status	Published - 1 Jan 2009

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abstract = "SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(II) EDTA](2-) by H2O2, in real time and it was shown that, in combination with other methods (e. g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.",

author = "R Evans and KB Henbest and MA Hayward and Melanie Britton and K Maeda and CR Timmel",

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AU - Britton, Melanie

AU - Maeda, K

AU - Timmel, CR

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N2 - SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(II) EDTA](2-) by H2O2, in real time and it was shown that, in combination with other methods (e. g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.

AB - SQUID magnetometry, normally used to characterise the properties of solids, was used to follow a clock reaction in solution, namely the auto-catalytic oxidation of [Co(II) EDTA](2-) by H2O2, in real time and it was shown that, in combination with other methods (e. g., magnetic resonance proton relaxation studies and UV-vis absorption analysis), SQUID magnetometry can be a powerful method in elucidating and interpreting the time-profile of chemical reactions so as long as reactants, intermediates and products have suitably large differences in their respective magnetic susceptibilities.

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DO - 10.1039/b819977a

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EP - 2469

JO - Dalton Transactions

JF - Dalton Transactions

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SQUID magnetometry as a tool for following a clock reaction in solution

Abstract

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