TY - JOUR
T1 - Solution Processing Route to Multifunctional Titania Thin Films: Highly Conductive and Photcatalytically Active Nb:TiO2
AU - Scanlon, David
AU - Bhachu, Davinder S.
AU - Sathasivam, Sanjayan
AU - Cibin, Giannantonio
AU - Carmalt, Claire J.
AU - Parkin, Ivan
PY - 2014/5/26
Y1 - 2014/5/26
N2 - This paper reports the synthesis of highly conductive niobium doped titanium dioxide (Nb:TiO2) films from the decomposition of Ti(OEt)4 with dopant quantities of Nb(OEt)5 by aerosol-assisted chemical vapor deposition (AACVD). Doping Nb into the Ti sites results in n-type conductivity, as determined by Hall effect measurements. The doped films display significantly improved electrical properties compared to pristine TiO2 films. For 5 at.% Nb in the films, the charge carrier concentration was 2 × 1021 cm−3 with a mobility of 2 cm2 V–1 s–1 . The corresponding sheet resistance is as low as 6.5 Ω sq–1 making the films suitable candidates for transparent conducting oxide (TCO) materials. This is, to the best of our knowledge, the lowest reported sheet resistance for Nb:TiO2 films synthesized by vapour deposition. The doped films are also blue in colour, with the intensity dependent on the Nb concentration in the films. A combination of synchrotron, laboratory and theoretical techniques confirmed niobium doping into the anatase TiO2 lattice. Computational methods also confirmed experimental results of both delocalized (Ti4+) and localized polaronic states (Ti3+) states. Additionally, the doped films also functioned as photocatalysts. Thus, Nb:TiO2 combines four functional properties (photocatalysis, electrical conductivity, optical transparency and blue colouration) within the same layer, making it a promising alternative to conventional TCO materials.
AB - This paper reports the synthesis of highly conductive niobium doped titanium dioxide (Nb:TiO2) films from the decomposition of Ti(OEt)4 with dopant quantities of Nb(OEt)5 by aerosol-assisted chemical vapor deposition (AACVD). Doping Nb into the Ti sites results in n-type conductivity, as determined by Hall effect measurements. The doped films display significantly improved electrical properties compared to pristine TiO2 films. For 5 at.% Nb in the films, the charge carrier concentration was 2 × 1021 cm−3 with a mobility of 2 cm2 V–1 s–1 . The corresponding sheet resistance is as low as 6.5 Ω sq–1 making the films suitable candidates for transparent conducting oxide (TCO) materials. This is, to the best of our knowledge, the lowest reported sheet resistance for Nb:TiO2 films synthesized by vapour deposition. The doped films are also blue in colour, with the intensity dependent on the Nb concentration in the films. A combination of synchrotron, laboratory and theoretical techniques confirmed niobium doping into the anatase TiO2 lattice. Computational methods also confirmed experimental results of both delocalized (Ti4+) and localized polaronic states (Ti3+) states. Additionally, the doped films also functioned as photocatalysts. Thus, Nb:TiO2 combines four functional properties (photocatalysis, electrical conductivity, optical transparency and blue colouration) within the same layer, making it a promising alternative to conventional TCO materials.
KW - Transparent conducting oxides
KW - photovoltaic
KW - aerosol assisted chemical vapour deposition synthesis
U2 - 10.1002/adfm.201400338
DO - 10.1002/adfm.201400338
M3 - Article
SN - 1616-301X
VL - 24
SP - 5075
EP - 5085
JO - Advanced Functional Materials
JF - Advanced Functional Materials
IS - 32
ER -