Side-chain supramolecular polymers employing conformer independent triple hydrogen bonding arrays

Adam Gooch; Natasha S. Murphy; Neil H. Thomson; Andrew J. Wilson

doi:10.1021/ma402069b

Side-chain supramolecular polymers employing conformer independent triple hydrogen bonding arrays

Adam Gooch, Natasha S. Murphy, Neil H. Thomson, Andrew J. Wilson^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

Derivatives of thymine have been extensively used to promote supramolecular materials assembly. Such derivatives can be synthetically challenging to access and may be susceptible to degradation. The current article uses a conformer-independent acceptor-donor-acceptor array (ureidopyrimidine) which forms moderate affinity interactions with diamidopyridine derivatives to effect supramolecular blend formation between polystyrene and poly(methyl methacrylate) polymers obtained by RAFT which have been functionalized with the hydrogen bonding motifs.

Original language	English
Pages (from-to)	9634-9641
Number of pages	8
Journal	Macromolecules
Volume	46
Issue number	24
DOIs	https://doi.org/10.1021/ma402069b
Publication status	Published - 23 Dec 2013

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma402069b

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abstract = "Derivatives of thymine have been extensively used to promote supramolecular materials assembly. Such derivatives can be synthetically challenging to access and may be susceptible to degradation. The current article uses a conformer-independent acceptor-donor-acceptor array (ureidopyrimidine) which forms moderate affinity interactions with diamidopyridine derivatives to effect supramolecular blend formation between polystyrene and poly(methyl methacrylate) polymers obtained by RAFT which have been functionalized with the hydrogen bonding motifs.",

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AB - Derivatives of thymine have been extensively used to promote supramolecular materials assembly. Such derivatives can be synthetically challenging to access and may be susceptible to degradation. The current article uses a conformer-independent acceptor-donor-acceptor array (ureidopyrimidine) which forms moderate affinity interactions with diamidopyridine derivatives to effect supramolecular blend formation between polystyrene and poly(methyl methacrylate) polymers obtained by RAFT which have been functionalized with the hydrogen bonding motifs.

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Side-chain supramolecular polymers employing conformer independent triple hydrogen bonding arrays

Abstract

ASJC Scopus subject areas

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