Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd-NHC complex

Benjamin J. Groombridge; Stephen M. Goldup; Igor Larrosa

doi:10.1039/c4cc08920k

Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd-NHC complex

Benjamin J. Groombridge, Stephen M. Goldup^*, Igor Larrosa

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

Abstract

We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.

Original language	English
Pages (from-to)	3832-3834
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	18
DOIs	https://doi.org/10.1039/c4cc08920k
Publication status	Published - 4 Mar 2015

Bibliographical note

Publisher Copyright:
© The Royal Society of Chemistry 2015.

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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abstract = "We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.",

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AU - Goldup, Stephen M.

AU - Larrosa, Igor

PY - 2015/3/4

Y1 - 2015/3/4

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AB - We report the first example of a general, exhaustive Pd-mediated cross-coupling of polychloroarenes in the presence of a deficit of nucleophiles, mediated by the highly active PEPPSI-IPent catalyst. Our results indicate that this catalyst system may be applicable to the pseudo-living polymerisation of chloroarene monomers.

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U2 - 10.1039/c4cc08920k

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Selective and general exhaustive cross-coupling of di-chloroarenes with a deficit of nucleophiles mediated by a Pd-NHC complex

Abstract

Bibliographical note

ASJC Scopus subject areas

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