(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation

Ahmed A. Fadhil; Anees A. Khadom; Hongfang Liu; Chaoyang Fu; Junlei Wang; Noor A. Fadhil; Hameed B. Mahood

doi:10.1016/j.molliq.2018.12.015

(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation

Ahmed A. Fadhil, Anees A. Khadom^*, Hongfang Liu, Chaoyang Fu, Junlei Wang, Noor A. Fadhil, Hameed B. Mahood

^*Corresponding author for this work

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

A study on the corrosion inhibition of N80 steel in 0.5 M HCl acid with (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole was undertaken by conducting electrochemical, weight loss, surface morphology, and FTIR measurements. The inhibition efficiency was found to exceed 95%. An excellent inhibitor performance was attained when a spontaneous layer was formed and adsorbed chemically on the surface of steel. The adsorption of inhibitor followed Langmuir adsorption isotherm. Meanwhile, the inhibitor was categorized as a mixed – type one. FTIR and surface morphology analysis was conducted to validate the results, whereas quantum chemical calculation was applied for justifying the inhibition process.

Original language	English
Pages (from-to)	503-518
Number of pages	16
Journal	Journal of Molecular Liquids
Volume	276
DOIs	https://doi.org/10.1016/j.molliq.2018.12.015
Publication status	Published - 15 Feb 2019

Bibliographical note

Publisher Copyright:
© 2018 Elsevier B.V.

Keywords

Acid corrosion
EIS
Inhibitor
Polarization
SEM

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry

Access to Document

10.1016/j.molliq.2018.12.015

Fingerprint

Dive into the research topics of '(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation'. Together they form a unique fingerprint.

Cite this

Fadhil, A. A., Khadom, A. A., Liu, H., Fu, C., Wang, J., Fadhil, N. A., & Mahood, H. B. (2019). (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation. Journal of Molecular Liquids, 276, 503-518. https://doi.org/10.1016/j.molliq.2018.12.015

@article{c52b77d1cc2b41218f199af46799882d,

title = "(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation",

abstract = "A study on the corrosion inhibition of N80 steel in 0.5 M HCl acid with (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole was undertaken by conducting electrochemical, weight loss, surface morphology, and FTIR measurements. The inhibition efficiency was found to exceed 95%. An excellent inhibitor performance was attained when a spontaneous layer was formed and adsorbed chemically on the surface of steel. The adsorption of inhibitor followed Langmuir adsorption isotherm. Meanwhile, the inhibitor was categorized as a mixed – type one. FTIR and surface morphology analysis was conducted to validate the results, whereas quantum chemical calculation was applied for justifying the inhibition process.",

keywords = "Acid corrosion, EIS, Inhibitor, Polarization, SEM",

author = "Fadhil, {Ahmed A.} and Khadom, {Anees A.} and Hongfang Liu and Chaoyang Fu and Junlei Wang and Fadhil, {Noor A.} and Mahood, {Hameed B.}",

note = "Publisher Copyright: {\textcopyright} 2018 Elsevier B.V.",

year = "2019",

month = feb,

day = "15",

doi = "10.1016/j.molliq.2018.12.015",

language = "English",

volume = "276",

pages = "503--518",

journal = "Journal of Molecular Liquids",

issn = "0167-7322",

publisher = "Elsevier",

}

Fadhil, AA, Khadom, AA, Liu, H, Fu, C, Wang, J, Fadhil, NA & Mahood, HB 2019, '(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation', Journal of Molecular Liquids, vol. 276, pp. 503-518. https://doi.org/10.1016/j.molliq.2018.12.015

(S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution: Gravimetrical, electrochemical, surface morphology and theoretical simulation. / Fadhil, Ahmed A.; Khadom, Anees A.; Liu, Hongfang et al.
In: Journal of Molecular Liquids, Vol. 276, 15.02.2019, p. 503-518.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole hydrochloride as corrosion inhibitor of steel in acidic solution

T2 - Gravimetrical, electrochemical, surface morphology and theoretical simulation

AU - Fadhil, Ahmed A.

AU - Khadom, Anees A.

AU - Liu, Hongfang

AU - Fu, Chaoyang

AU - Wang, Junlei

AU - Fadhil, Noor A.

AU - Mahood, Hameed B.

PY - 2019/2/15

Y1 - 2019/2/15

N2 - A study on the corrosion inhibition of N80 steel in 0.5 M HCl acid with (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole was undertaken by conducting electrochemical, weight loss, surface morphology, and FTIR measurements. The inhibition efficiency was found to exceed 95%. An excellent inhibitor performance was attained when a spontaneous layer was formed and adsorbed chemically on the surface of steel. The adsorption of inhibitor followed Langmuir adsorption isotherm. Meanwhile, the inhibitor was categorized as a mixed – type one. FTIR and surface morphology analysis was conducted to validate the results, whereas quantum chemical calculation was applied for justifying the inhibition process.

AB - A study on the corrosion inhibition of N80 steel in 0.5 M HCl acid with (S)‑6‑Phenyl‑2,3,5,6‑tetrahydroimidazo[2,1‑b] thiazole was undertaken by conducting electrochemical, weight loss, surface morphology, and FTIR measurements. The inhibition efficiency was found to exceed 95%. An excellent inhibitor performance was attained when a spontaneous layer was formed and adsorbed chemically on the surface of steel. The adsorption of inhibitor followed Langmuir adsorption isotherm. Meanwhile, the inhibitor was categorized as a mixed – type one. FTIR and surface morphology analysis was conducted to validate the results, whereas quantum chemical calculation was applied for justifying the inhibition process.

KW - Acid corrosion

KW - EIS

KW - Inhibitor

KW - Polarization

KW - SEM

UR - http://www.scopus.com/inward/record.url?scp=85058061432&partnerID=8YFLogxK

U2 - 10.1016/j.molliq.2018.12.015

DO - 10.1016/j.molliq.2018.12.015

M3 - Article

AN - SCOPUS:85058061432

SN - 0167-7322

VL - 276

SP - 503

EP - 518

JO - Journal of Molecular Liquids

JF - Journal of Molecular Liquids

ER -