Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector

Arnaud Tron; Isabelle Pianet; Alberto Martinez-Cuezva; James H R Tucker; Luca Pisciottani; Mateo Alajarin; Jose Berna; Nathan D McClenaghan

doi:10.1021/acs.orglett.6b03457

Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector

Arnaud Tron, Isabelle Pianet, Alberto Martinez-Cuezva, James H R Tucker, Luca Pisciottani, Mateo Alajarin, Jose Berna, Nathan D McClenaghan

Chemistry

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19 Citations (Scopus)

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Abstract

A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.

Original language	English
Pages (from-to)	154-157
Number of pages	4
Journal	Organic Letters
Volume	19
Issue number	1
Early online date	9 Dec 2016
DOIs	https://doi.org/10.1021/acs.orglett.6b03457
Publication status	Published - 6 Jan 2017

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Tron_et_al_Remote_Photoregulated_Ring_Gliding_Organic_Letters
The Final Version of Record is available online at: http://dx.doi.org/10.1021/acs.orglett.6b03457 Checked 21/2/2017
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Cite this

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abstract = "A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.",

author = "Arnaud Tron and Isabelle Pianet and Alberto Martinez-Cuezva and Tucker, {James H R} and Luca Pisciottani and Mateo Alajarin and Jose Berna and McClenaghan, {Nathan D}",

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AU - Tron, Arnaud

AU - Pianet, Isabelle

AU - Martinez-Cuezva, Alberto

AU - Tucker, James H R

AU - Pisciottani, Luca

AU - Alajarin, Mateo

AU - Berna, Jose

AU - McClenaghan, Nathan D

PY - 2017/1/6

Y1 - 2017/1/6

N2 - A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.

AB - A molecular barbiturate messenger, which is reversibly released/captured by a photoswitchable artificial molecular receptor, is shown to act as an effector to control ring gliding on a distant hydrogen-bonding [2]rotaxane. Thus, light-driven chemical communication governing the operation of a remote molecular machine is demonstrated using an information-rich neutral molecule.

U2 - 10.1021/acs.orglett.6b03457

DO - 10.1021/acs.orglett.6b03457

M3 - Article

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VL - 19

SP - 154

EP - 157

JO - Organic Letters

JF - Organic Letters

IS - 1

ER -

Remote Photoregulated Ring Gliding in a [2]Rotaxane via a Molecular Effector

Abstract

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