Polymers from macrolactones: from pheromones to functional materials

James A. Wilson; Zeliha Ates; Robin L. Pflughaupt; Andrew P. Dove; Andreas Heise

doi:10.1016/j.progpolymsci.2019.02.005

Polymers from macrolactones: from pheromones to functional materials

James A. Wilson, Zeliha Ates, Robin L. Pflughaupt, Andrew P. Dove, Andreas Heise

Chemistry

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

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Abstract

Recent advances in the ring-opening polymerization (ROP) of macrolactones (MLs) have afforded access to novel, potentially degradable polymeric materials featuring long aliphatic chains. These developments extend the synthetic robustness and versatility of ROP to a greater range of interesting monomers, many of which can be derived from sustainable or renewable feedstocks, to access polymeric materials boasting a diversity of properties and potential applications. This review discusses current strategies to catalyse the ROP of MLs, comparing and contrasting them with those known for the ROP of small and medium sized lactones, and highlights recent developments in the preparation, functionalization, and application of materials featuring poly(macrolactone)s (PMLs).

Original language	English
Pages (from-to)	29-50
Journal	Progress in Polymer Science
Volume	91
Early online date	16 Feb 2019
DOIs	https://doi.org/10.1016/j.progpolymsci.2019.02.005
Publication status	Published - 1 Apr 2019

Keywords

aliphatic polyesters
catalysis
macrolactones
renewable polymers
ring-opening polymerization

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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Wilson_et_al_Polymers_from_macrolactones_Progress_in_Polymer_Science_2019Accepted author manuscript, 1.99 MBLicence: Creative Commons: Attribution-NonCommercial-NoDerivs (CC BY-NC-ND)

https://www.sciencedirect.com/science/article/pii/S0079670018304076Licence: None: All rights reserved

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title = "Polymers from macrolactones: from pheromones to functional materials",

abstract = "Recent advances in the ring-opening polymerization (ROP) of macrolactones (MLs) have afforded access to novel, potentially degradable polymeric materials featuring long aliphatic chains. These developments extend the synthetic robustness and versatility of ROP to a greater range of interesting monomers, many of which can be derived from sustainable or renewable feedstocks, to access polymeric materials boasting a diversity of properties and potential applications. This review discusses current strategies to catalyse the ROP of MLs, comparing and contrasting them with those known for the ROP of small and medium sized lactones, and highlights recent developments in the preparation, functionalization, and application of materials featuring poly(macrolactone)s (PMLs).",

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AU - Wilson, James A.

AU - Ates, Zeliha

AU - Pflughaupt, Robin L.

AU - Dove, Andrew P.

AU - Heise, Andreas

PY - 2019/4/1

Y1 - 2019/4/1

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AB - Recent advances in the ring-opening polymerization (ROP) of macrolactones (MLs) have afforded access to novel, potentially degradable polymeric materials featuring long aliphatic chains. These developments extend the synthetic robustness and versatility of ROP to a greater range of interesting monomers, many of which can be derived from sustainable or renewable feedstocks, to access polymeric materials boasting a diversity of properties and potential applications. This review discusses current strategies to catalyse the ROP of MLs, comparing and contrasting them with those known for the ROP of small and medium sized lactones, and highlights recent developments in the preparation, functionalization, and application of materials featuring poly(macrolactone)s (PMLs).

KW - aliphatic polyesters

KW - catalysis

KW - macrolactones

KW - renewable polymers

KW - ring-opening polymerization

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JO - Progress in Polymer Science

JF - Progress in Polymer Science

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Polymers from macrolactones: from pheromones to functional materials

Abstract

Keywords

UN SDGs

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