Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra

Belen Lerma-Berlanga; Javier Castells-Gil; Carolina R. Ganivet; Neyvis Almora-Barrios; Javier Gonzalez-Platas; Oscar Fabelo; Natalia M. Padial; Carlos Marti-Gastaldo

doi:10.1021/jacs.1c09278

Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra

Belen Lerma-Berlanga
, Javier Castells-Gil
, Carolina R. Ganivet
, Neyvis Almora-Barrios
, Javier Gonzalez-Platas
, Oscar Fabelo
, Natalia M. Padial
, Carlos Marti-Gastaldo^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Letter › peer-review

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Abstract

Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m²·g^-1.

Original language	English
Pages (from-to)	21195-21199
Number of pages	5
Journal	Journal of the American Chemical Society
Volume	143
Issue number	50
Early online date	8 Dec 2021
DOIs	https://doi.org/10.1021/jacs.1c09278
Publication status	Published - 22 Dec 2021

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ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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LermaBerlangaB2021PermanentFinal published version, 3.08 MBLicence: Creative Commons: Attribution (CC BY)

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title = "Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra",

abstract = "Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g-1.",

author = "Belen Lerma-Berlanga and Javier Castells-Gil and Ganivet, \{Carolina R.\} and Neyvis Almora-Barrios and Javier Gonzalez-Platas and Oscar Fabelo and Padial, \{Natalia M.\} and Carlos Marti-Gastaldo",

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T1 - Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra

AU - Lerma-Berlanga, Belen

AU - Castells-Gil, Javier

AU - Ganivet, Carolina R.

AU - Almora-Barrios, Neyvis

AU - Gonzalez-Platas, Javier

AU - Fabelo, Oscar

AU - Padial, Natalia M.

AU - Marti-Gastaldo, Carlos

PY - 2021/12/22

Y1 - 2021/12/22

N2 - Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g-1.

AB - Following the synthesis of hydroxamate titanium-organic frameworks, we now extend these siderophore-type linkers to the assembly of the first titanium-organic polyhedra displaying permanent porosity. Mixed-linker versions of this molecular cage (cMUV-11) are also used to demonstrate the effect of pore chemistry in accessing high surface areas of near 1200 m2·g-1.

UR - https://www.scopus.com/pages/publications/85121051978

U2 - 10.1021/jacs.1c09278

DO - 10.1021/jacs.1c09278

M3 - Letter

C2 - 34877864

AN - SCOPUS:85121051978

SN - 0002-7863

VL - 143

SP - 21195

EP - 21199

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 50

ER -

Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra

Abstract

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