Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

Akina Yoshizawa; Antonio Feula; Andrew G Leach; Louise Male; John S Fossey

doi:10.3389/fchem.2018.00211

Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

Akina Yoshizawa, Antonio Feula, Andrew G Leach, Louise Male, John S Fossey

Chemistry

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

381 Downloads (Pure)

Abstract

Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

Original language	English
Article number	211
Journal	Frontiers in Chemistry
Volume	6
DOIs	https://doi.org/10.3389/fchem.2018.00211
Publication status	Published - 21 Jun 2018

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Yoshizawa_et_al_Palladium_Platinum_Frontiers_ChemistryFinal published version, 1.96 MBLicence: Creative Commons: Attribution (CC BY)
Yoshizawa_et_al_Palladium_and_Platinum_Frontiers_in_Chemistry_2018
Checked for eligibility 22/10/2018 First published in Frontiers in Chemistry https://doi.org/10.3389/fchem.2018.00211
Final published version, 1.96 MBLicence: Creative Commons: Attribution (CC BY)

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Boronic Acids for Dye Sensitised Solar Cells
Fossey, J. (Principal Investigator)
Engineering & Physical Science Research Council
23/04/12 → 22/04/14
Project: Research

Cite this

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title = "Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes",

abstract = "Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.",

author = "Akina Yoshizawa and Antonio Feula and Leach, {Andrew G} and Louise Male and Fossey, {John S}",

year = "2018",

month = jun,

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doi = "10.3389/fchem.2018.00211",

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T1 - Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

AU - Yoshizawa, Akina

AU - Feula, Antonio

AU - Leach, Andrew G

AU - Male, Louise

AU - Fossey, John S

PY - 2018/6/21

Y1 - 2018/6/21

N2 - Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

AB - Seven N,N'-palladium(II) chloride complexes, one N,N'-palladium(II) acetate complex of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Two platinum(II) chloride N,N'-complexes of 2,4-cis-azetidines where prepared and analyzed by single crystal XRD. Computational analysis and determination of the %Vbur was examined conducted. A CNN' metallocyclic complex was prepared by oxidative addition of palladium(0) to an ortho bromo 2,4-cis-disubstituted azetidine and its crystal structure displays a slightly pyramidalized metal-ligand orientation.

U2 - 10.3389/fchem.2018.00211

DO - 10.3389/fchem.2018.00211

M3 - Article

C2 - 29977888

SN - 2296-2646

VL - 6

JO - Frontiers in Chemistry

JF - Frontiers in Chemistry

M1 - 211

ER -

Palladium and Platinum 2,4-cis-amino Azetidine and Related Complexes

Abstract

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Boronic Acids for Dye Sensitised Solar Cells

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