Organic coating reduces hygroscopic growth of phase-separated aerosol particles

Weijun Li, Xiaome Teng, Xiyao Chen, Lei Liu, Liang Xu, Jian Zhang, Yuanyuan Wang, Yue Zhang, Zongbo Shi

Research output: Contribution to journalArticlepeer-review

Abstract

A large fraction of secondary aerosol particles are liquid–liquid phase-separated with an organic shell and an inorganic core. This has the potential to regulate the hygroscopicity of such particles, with significant implications for their optical properties, reactivity, and lifetime. However, it is unclear how this phase separation affects the hygroscopic growth of the particles. Here, we showed a large variation in hygroscopic growth (e.g., 1.14–1.32 under a relative humidity (RH) of 90%) of particles from the forest and urban atmosphere, which had different average core–shell ratios. For this reason, a controlled laboratory experiment further quantifies the impact of the organic shell on particle growth with different RH values. Laboratory experiments demonstrated that (NH4)2SO4 particles with thicker secondary organic shells have a lower growth factor at an RH below 94%. Organic shells started to deliquesce first (RH > 50%) and the phase changes of sulfate cores from solid to liquid took place at an RH higher than 80% as deliquescence relative humidity of pure (NH4)2SO4. Our study provides the first direct evidence on an individual particle basis that hygroscopic growth behavior of phase-separated particles is dependent on the thickness of organic shells, highlighting the importance of organic coating in water uptake and possible heterogeneous reactions of the phase-separated particles.

Original languageEnglish
Pages (from-to)16339-16346
Number of pages8
JournalEnvironmental Science and Technology
Volume55
Issue number24
Early online date12 Dec 2021
DOIs
Publication statusPublished - 21 Dec 2021

Bibliographical note

Funding Information:
Cryo-EM characterization was conducted at the Center of Cryo-Electron Microscopy, Zhejiang University, with the assistance of L. Wu. We gratefully acknowledge Shujia Zhang to conduct part of the laboratory experiments. The work was funded by the National Natural Science Foundation of China (91844301 and 42075096) and Zhejiang Provincial Natural Science Foundation of China (LZ19D050001). All the data are presented in the paper.

Publisher Copyright:
© 2021 American Chemical Society

Keywords

  • aerosol
  • hygroscopicity
  • liquid−liquid phase separation
  • particle phase

ASJC Scopus subject areas

  • Chemistry(all)
  • Environmental Chemistry

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