One-step solvothermal synthesis of Fe-doped BiOI film with enhanced photocatalytic performance

Miaomiao Wang; Jianzhi Gao; Gangqiang Zhu; Ning Li; Runliang Zhu; Xiumei Wei; Quanmin Guo; Peng Liu

doi:10.1039/C6RA21350B

One-step solvothermal synthesis of Fe-doped BiOI film with enhanced photocatalytic performance

Miaomiao Wang
, Jianzhi Gao
, Gangqiang Zhu
, Ning Li
, Runliang Zhu
, Xiumei Wei
, Quanmin Guo
, Peng Liu

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Ultrathin nanosheets consisting of Fe-doped BiOI were obtained on a FTO (SnO2:F) glass substrate via a simple solvothermal process. High-resolution transmission electron microscopic analysis indicates that the ultrathin nanosheets are exposed with {001} facets. The Fe-doped BiOI film has a higher photocatalytic activity for degrading Rhodamine B under visible light irradiation in comparison with the undoped BiOI films. The photocatalytic activity reached a maximum when the Fe doping concentration was 7%. It is believed that an optimal concentration of Fe3+ ions improves the electron–hole separation efficiency, hence improving the degradation rate of Rhodamine B. Scavenger test results indicate that the photo-generated h+ and ˙O2− play an important role in the degradation of Rhodamine B. A possible photocatalytic degradation mechanism for Rhodamine B by Fe-doped BiOI film is presented.

Original language	English
Journal	RSC Advances
Volume	6
Issue number	108
Early online date	26 Oct 2016
DOIs	https://doi.org/10.1039/C6RA21350B
Publication status	E-pub ahead of print - 26 Oct 2016

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title = "One-step solvothermal synthesis of Fe-doped BiOI film with enhanced photocatalytic performance",

abstract = "Ultrathin nanosheets consisting of Fe-doped BiOI were obtained on a FTO (SnO2:F) glass substrate via a simple solvothermal process. High-resolution transmission electron microscopic analysis indicates that the ultrathin nanosheets are exposed with \{001\} facets. The Fe-doped BiOI film has a higher photocatalytic activity for degrading Rhodamine B under visible light irradiation in comparison with the undoped BiOI films. The photocatalytic activity reached a maximum when the Fe doping concentration was 7\%. It is believed that an optimal concentration of Fe3+ ions improves the electron–hole separation efficiency, hence improving the degradation rate of Rhodamine B. Scavenger test results indicate that the photo-generated h+ and ˙O2− play an important role in the degradation of Rhodamine B. A possible photocatalytic degradation mechanism for Rhodamine B by Fe-doped BiOI film is presented.",

author = "Miaomiao Wang and Jianzhi Gao and Gangqiang Zhu and Ning Li and Runliang Zhu and Xiumei Wei and Quanmin Guo and Peng Liu",

year = "2016",

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doi = "10.1039/C6RA21350B",

language = "English",

volume = "6",

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issn = "2046-2069",

publisher = "Royal Society of Chemistry",

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TY - JOUR

T1 - One-step solvothermal synthesis of Fe-doped BiOI film with enhanced photocatalytic performance

AU - Wang, Miaomiao

AU - Gao, Jianzhi

AU - Zhu, Gangqiang

AU - Li, Ning

AU - Zhu, Runliang

AU - Wei, Xiumei

AU - Guo, Quanmin

AU - Liu, Peng

PY - 2016/10/26

Y1 - 2016/10/26

N2 - Ultrathin nanosheets consisting of Fe-doped BiOI were obtained on a FTO (SnO2:F) glass substrate via a simple solvothermal process. High-resolution transmission electron microscopic analysis indicates that the ultrathin nanosheets are exposed with {001} facets. The Fe-doped BiOI film has a higher photocatalytic activity for degrading Rhodamine B under visible light irradiation in comparison with the undoped BiOI films. The photocatalytic activity reached a maximum when the Fe doping concentration was 7%. It is believed that an optimal concentration of Fe3+ ions improves the electron–hole separation efficiency, hence improving the degradation rate of Rhodamine B. Scavenger test results indicate that the photo-generated h+ and ˙O2− play an important role in the degradation of Rhodamine B. A possible photocatalytic degradation mechanism for Rhodamine B by Fe-doped BiOI film is presented.

AB - Ultrathin nanosheets consisting of Fe-doped BiOI were obtained on a FTO (SnO2:F) glass substrate via a simple solvothermal process. High-resolution transmission electron microscopic analysis indicates that the ultrathin nanosheets are exposed with {001} facets. The Fe-doped BiOI film has a higher photocatalytic activity for degrading Rhodamine B under visible light irradiation in comparison with the undoped BiOI films. The photocatalytic activity reached a maximum when the Fe doping concentration was 7%. It is believed that an optimal concentration of Fe3+ ions improves the electron–hole separation efficiency, hence improving the degradation rate of Rhodamine B. Scavenger test results indicate that the photo-generated h+ and ˙O2− play an important role in the degradation of Rhodamine B. A possible photocatalytic degradation mechanism for Rhodamine B by Fe-doped BiOI film is presented.

UR - https://www.scopus.com/pages/publications/84995665291

U2 - 10.1039/C6RA21350B

DO - 10.1039/C6RA21350B

M3 - Article

SN - 2046-2069

VL - 6

JO - RSC Advances

JF - RSC Advances

IS - 108

ER -

One-step solvothermal synthesis of Fe-doped BiOI film with enhanced photocatalytic performance

Abstract

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