Observation of the Stark effect in autoionising Rydberg states of molecular hydrogen

H FIELDING; T SOFTLEY

doi:10.1016/S0009-2614(91)85047-Z

Observation of the Stark effect in autoionising Rydberg states of molecular hydrogen

H FIELDING, T SOFTLEY

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Abstract

The dc Stark effect is studied for autoionising Rydberg states of H2 converging on the ν+=2 ionisation limit. The levels (n = 13–22) are excited from the ground state using a coherent XUV source (bandwidth ≈ 1 cm−1) and are strongly perturbed by the field (15–2000 V/cm). Many new states are observed, including the high-/hydrogenic manifolds. A detailed Stark map is obtained for the first time, and a matrix diagonalisation calculation of field-induced state mixing is carried out to explain some of the observed features.

Original language	English
Pages (from-to)	199-205
Number of pages	7
Journal	Chemical Physics Letters
Volume	185
Issue number	3-4
DOIs	https://doi.org/10.1016/S0009-2614(91)85047-Z
Publication status	Published - 1 Oct 1991

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title = "Observation of the Stark effect in autoionising Rydberg states of molecular hydrogen",

abstract = "The dc Stark effect is studied for autoionising Rydberg states of H2 converging on the ν+=2 ionisation limit. The levels (n = 13–22) are excited from the ground state using a coherent XUV source (bandwidth ≈ 1 cm−1) and are strongly perturbed by the field (15–2000 V/cm). Many new states are observed, including the high-/hydrogenic manifolds. A detailed Stark map is obtained for the first time, and a matrix diagonalisation calculation of field-induced state mixing is carried out to explain some of the observed features.",

author = "H FIELDING and T SOFTLEY",

year = "1991",

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doi = "10.1016/S0009-2614(91)85047-Z",

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T1 - Observation of the Stark effect in autoionising Rydberg states of molecular hydrogen

AU - FIELDING, H

AU - SOFTLEY, T

PY - 1991/10/1

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N2 - The dc Stark effect is studied for autoionising Rydberg states of H2 converging on the ν+=2 ionisation limit. The levels (n = 13–22) are excited from the ground state using a coherent XUV source (bandwidth ≈ 1 cm−1) and are strongly perturbed by the field (15–2000 V/cm). Many new states are observed, including the high-/hydrogenic manifolds. A detailed Stark map is obtained for the first time, and a matrix diagonalisation calculation of field-induced state mixing is carried out to explain some of the observed features.

AB - The dc Stark effect is studied for autoionising Rydberg states of H2 converging on the ν+=2 ionisation limit. The levels (n = 13–22) are excited from the ground state using a coherent XUV source (bandwidth ≈ 1 cm−1) and are strongly perturbed by the field (15–2000 V/cm). Many new states are observed, including the high-/hydrogenic manifolds. A detailed Stark map is obtained for the first time, and a matrix diagonalisation calculation of field-induced state mixing is carried out to explain some of the observed features.

U2 - 10.1016/S0009-2614(91)85047-Z

DO - 10.1016/S0009-2614(91)85047-Z

M3 - Article

SN - 0009-2614

VL - 185

SP - 199

EP - 205

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3-4

ER -

Observation of the Stark effect in autoionising Rydberg states of molecular hydrogen

Abstract

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