Nuclear hyperfine structure in the electronic millimetre wave spectrum of H2+

Alan Carrington; Christine A. Leach; Mark R. Viant

doi:10.1016/0009-2614(93)85520-X

Nuclear hyperfine structure in the electronic millimetre wave spectrum of H₂⁺

Alan Carrington^*
, Christine A. Leach
, Mark R. Viant

^*Corresponding author for this work

Biosciences

Research output: Contribution to journal › Article › peer-review

Abstract

The 2pσ_u υ=0, N=2-lsσ_g υ=18, N=3 transition in H₂⁺ has been observed at 156632.8 MHz. This transition shows a characteristic structure which we assign in terms of hyperfine, fine and electronic g/u symmetry-breaking effects.

Original language	English
Pages (from-to)	77-82
Number of pages	6
Journal	Chemical Physics Letters
Volume	206
Issue number	1-4
DOIs	https://doi.org/10.1016/0009-2614(93)85520-X
Publication status	Published - 30 Apr 1993

Bibliographical note

Funding Information:
We thank Dr. R.E. Moss for many helpful conversations, and Dr. R.A. Kennedy for providing unpublished results. AC thanks the Royal Society for a Research Professorship, CAL thanks the SERC for an Advanced Fellowship and MRV thanks the BP International Limited for a research studentship. We are indebted to the SERC for grants towards the purchase of equipment.

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/0009-2614(93)85520-X

Cite this

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title = "Nuclear hyperfine structure in the electronic millimetre wave spectrum of H2+",

abstract = "The 2pσu υ=0, N=2-lsσg υ=18, N=3 transition in H2+ has been observed at 156632.8 MHz. This transition shows a characteristic structure which we assign in terms of hyperfine, fine and electronic g/u symmetry-breaking effects.",

author = "Alan Carrington and Leach, \{Christine A.\} and Viant, \{Mark R.\}",

note = "Funding Information: We thank Dr. R.E. Moss for many helpful conversations, and Dr. R.A. Kennedy for providing unpublished results. AC thanks the Royal Society for a Research Professorship, CAL thanks the SERC for an Advanced Fellowship and MRV thanks the BP International Limited for a research studentship. We are indebted to the SERC for grants towards the purchase of equipment.",

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N2 - The 2pσu υ=0, N=2-lsσg υ=18, N=3 transition in H2+ has been observed at 156632.8 MHz. This transition shows a characteristic structure which we assign in terms of hyperfine, fine and electronic g/u symmetry-breaking effects.

AB - The 2pσu υ=0, N=2-lsσg υ=18, N=3 transition in H2+ has been observed at 156632.8 MHz. This transition shows a characteristic structure which we assign in terms of hyperfine, fine and electronic g/u symmetry-breaking effects.

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