Abstract
We describe the synthesis of N-functionalised phosphinecarboxamides obtained by reaction of the 2-phosphaethynolate anion (PCO−) with diamines, specifically hydrazine, methylenediamine and ethylenediamine, in the presence of acid. The resulting neutral compounds can be deprotonated to generate phosphide anions that, when further reacted with electrophiles, form secondary phosphines.
Original language | English |
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Pages (from-to) | 6991-6996 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 20 |
Early online date | 28 Apr 2021 |
DOIs | |
Publication status | E-pub ahead of print - 28 Apr 2021 |
ASJC Scopus subject areas
- Inorganic Chemistry