Novel primary phosphinecarboxamides derived from diamines

Erica N. Faria; Andrew R. Jupp; Jose M. Goicoechea

doi:10.1039/D1DT01198G

Novel primary phosphinecarboxamides derived from diamines

Erica N. Faria, Andrew R. Jupp, Jose M. Goicoechea

Chemistry

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Abstract

We describe the synthesis of N-functionalised phosphinecarboxamides obtained by reaction of the 2-phosphaethynolate anion (PCO−) with diamines, specifically hydrazine, methylenediamine and ethylenediamine, in the presence of acid. The resulting neutral compounds can be deprotonated to generate phosphide anions that, when further reacted with electrophiles, form secondary phosphines.

Original language	English
Pages (from-to)	6991-6996
Journal	Dalton Transactions
Volume	50
Issue number	20
Early online date	28 Apr 2021
DOIs	https://doi.org/10.1039/D1DT01198G
Publication status	E-pub ahead of print - 28 Apr 2021

ASJC Scopus subject areas

Inorganic Chemistry

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Novel primary phosphinecarboxamides derived from diamines

Abstract

ASJC Scopus subject areas

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