Novel CoVO/WxOy composites for methylene blue photodegradation and electrocatalytic applications

  • Areej Zubair
  • , Faisal Nawaz*
  • , Masood ul Hassan Farooq*
  • , Iqra Fareed
  • , Muhammad Danish Khan
  • , Zulfiqar Ali
  • , Mariam Nawaz
  • , Hafiza Sadia Anam
  • , Muhammad Tahir
  • , Faheem K. Butt*
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

To address environmental and energy concerns, CoVO/WxOy nanocomposites are hydrothermally fabricated and their structural and chemical properties are examined using XRD and FTIR. The surface morphology and optical characteristics are investigated with the help of FESEM and UV–Visible spectroscopy, respectively. CoVO/WxOy exhibits increased photocatalytic efficacy towards methylene blue degradation, attributed to its unique properties. Furthermore, the interface of CoVO/WxOy follows a Z-scheme mechanism for efficient charge transfer, with ·OH identified as the most reactive species. The composite catalyst also displays exceptional stability. CoVO/WxOy also presents the capability to produce H2 and O2 from water splitting at small overpotential values. These investigations are supported by small tafel slope, Cdl value and electrochemical active surface area. These findings suggest that CoVO/WxOy hold great promise for use in environmental remediation and sustainable energy generation.

Original languageEnglish
Article number109104
Number of pages13
JournalMaterials Science in Semiconductor Processing
Volume186
Early online date15 Nov 2024
DOIs
Publication statusPublished - Feb 2025

Bibliographical note

Publisher Copyright:
© 2024 Elsevier Ltd

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 7 - Affordable and Clean Energy
    SDG 7 Affordable and Clean Energy

Keywords

  • Cobalt vanadate
  • HER
  • Methylene blue
  • OER
  • Tafel slope
  • WO

ASJC Scopus subject areas

  • General Materials Science
  • Condensed Matter Physics
  • Mechanics of Materials
  • Mechanical Engineering

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