Nitrile Oxide Cycloadditions in Supercritical Carbon Dioxide

CK Lee; AB Holmes; Bushra Al-Duri; Gary Leeke; Regina Santos; Jonathan Seville

doi:10.1039/b411561a

Nitrile Oxide Cycloadditions in Supercritical Carbon Dioxide

CK Lee
, AB Holmes
, Bushra Al-Duri
, Gary Leeke
, Regina Santos
, Jonathan Seville

Chemical Engineering

Research output: Contribution to journal › Article

11 Citations (Scopus)

Abstract

The regioselectivity of dipolar cycloadditions of mesitonitrile oxide to various dipolarophiles in supercritical carbon dioxide can be tuned by changes in density, the magnesium bromide-mediated cycloaddition to pent-1-en-3-ol proceeding with higher stereoselectivity than in most conventional solvents.

Original language	English
Pages (from-to)	2622-2623
Number of pages	2
Journal	Chemical Communications
Volume	22
DOIs	https://doi.org/10.1039/b411561a
Publication status	Published - 1 Jan 2004

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10.1039/b411561a

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title = "Nitrile Oxide Cycloadditions in Supercritical Carbon Dioxide",

abstract = "The regioselectivity of dipolar cycloadditions of mesitonitrile oxide to various dipolarophiles in supercritical carbon dioxide can be tuned by changes in density, the magnesium bromide-mediated cycloaddition to pent-1-en-3-ol proceeding with higher stereoselectivity than in most conventional solvents.",

author = "CK Lee and AB Holmes and Bushra Al-Duri and Gary Leeke and Regina Santos and Jonathan Seville",

year = "2004",

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doi = "10.1039/b411561a",

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T1 - Nitrile Oxide Cycloadditions in Supercritical Carbon Dioxide

AU - Lee, CK

AU - Holmes, AB

AU - Al-Duri, Bushra

AU - Leeke, Gary

AU - Santos, Regina

AU - Seville, Jonathan

PY - 2004/1/1

Y1 - 2004/1/1

N2 - The regioselectivity of dipolar cycloadditions of mesitonitrile oxide to various dipolarophiles in supercritical carbon dioxide can be tuned by changes in density, the magnesium bromide-mediated cycloaddition to pent-1-en-3-ol proceeding with higher stereoselectivity than in most conventional solvents.

AB - The regioselectivity of dipolar cycloadditions of mesitonitrile oxide to various dipolarophiles in supercritical carbon dioxide can be tuned by changes in density, the magnesium bromide-mediated cycloaddition to pent-1-en-3-ol proceeding with higher stereoselectivity than in most conventional solvents.

UR - https://www.scopus.com/pages/publications/9944229541

U2 - 10.1039/b411561a

DO - 10.1039/b411561a

M3 - Article

SN - 1364-548X

VL - 22

SP - 2622

EP - 2623

JO - Chemical Communications

JF - Chemical Communications

ER -

Nitrile Oxide Cycloadditions in Supercritical Carbon Dioxide

Abstract

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