Abstract
The reaction of 4'-phenyl-2,2':6', 2"-terpyridine I with nickel(II) chloride gives a 1: 1 adduct which we have structurally characterised and shown to be comprised of two species of stoichiometry {Ni(I)Cl-2}; the first is a five-coordinate [Ni(I)Cl-2] complex and the other is a dinuclear species containing two six-coordinate nickel centres [(I)ClNi(mu-Cl)(2)Ni(I)Cl]. (C) 2002 Elsevier Science B.V. All rights reserved.
| Original language | English |
|---|---|
| Pages (from-to) | 519-521 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry Communications |
| Volume | 5 |
| Issue number | 7 |
| Publication status | Published - 1 Jul 2002 |
Keywords
- 2,2 ': 6 ',2 ''-terpyridine
- supramolecular chemistry
- crystal structure
- nickel complex