TY - CHAP
T1 - Monitoring in situ Mechanochemical Reactions
AU - Emmerling, Franziska
AU - Michalchuk, Adam al
PY - 2025/1/31
Y1 - 2025/1/31
N2 - Mechanochemical reactions offer an environmentally friendly alternative to traditional synthesis methods, aligning with green chemistry principles. This chapter reviews advances in time-resolved in situ (TRIS) monitoring techniques, including synchrotron X-ray diffraction, X-ray adsorption and Raman spectroscopy. We will summarize key milestones in the development of TRIS techniques for monitoring mechanochemical reactions and discuss how they provide new insights into reaction pathways, kinetics, and experimental parameter design. The strengths and limitations of TRIS approaches are discussed, highlighting the benefits of combining complementary methods. By enhancing mechanistic understanding, these TRIS techniques facilitate the rational design and optimization of sustainable mechanochemical syntheses in chemistry and materials science.
AB - Mechanochemical reactions offer an environmentally friendly alternative to traditional synthesis methods, aligning with green chemistry principles. This chapter reviews advances in time-resolved in situ (TRIS) monitoring techniques, including synchrotron X-ray diffraction, X-ray adsorption and Raman spectroscopy. We will summarize key milestones in the development of TRIS techniques for monitoring mechanochemical reactions and discuss how they provide new insights into reaction pathways, kinetics, and experimental parameter design. The strengths and limitations of TRIS approaches are discussed, highlighting the benefits of combining complementary methods. By enhancing mechanistic understanding, these TRIS techniques facilitate the rational design and optimization of sustainable mechanochemical syntheses in chemistry and materials science.
UR - https://shop.elsevier.com/books/reference-module-in-chemistry-molecular-sciences-and-chemical-engineering/elsevier/978-0-12-409547-2
UR - https://www.scopus.com/pages/publications/105013697715
U2 - 10.1016/B978-0-443-15742-4.00126-5
DO - 10.1016/B978-0-443-15742-4.00126-5
M3 - Chapter
BT - Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
PB - Elsevier
ER -