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Abstract
A numerical simulation is designed in order to better understand the selective catalytic reduction of NO2 by propane (C3H8-SCR) in the presence of hydrogen. The simulation was designed for a single channel of a monolith typical for automotive catalytic converters, coated with a silver alumina catalyst (Ag/Al2O3). The complicated physical and chemical processes occurring during the reactions are solved by computational fluid dynamics (CFD) coupled with a surface-reaction mechanism. This mechanism is developed based on detailed microkinetic analysis. The elementary-step-like surface reaction mechanism (consisting of 94 reactions, 24 gas-phase species and 24 adsorbed surface species) is applied to investigate the effect on the conversion of NO2 to N-2 Of Chemical kinetic Steps, such as intermediate species. Results from the modelling emphatically agree with the experimental data. The modelling can predict the NO2 conversion at various operating conditions. Furthermore, the modelling can also provide information that is difficult to measure, for example predicts the channel wall temperature and surface coverage of surface species. (C) 2011 Elsevier B.V. All rights reserved.
Original language | English |
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Pages (from-to) | 165-177 |
Number of pages | 13 |
Journal | Applied Catalysis B: Environmental |
Volume | 111 |
DOIs | |
Publication status | Published - 1 Jan 2012 |
Keywords
- HC-SCR
- Ag/Al2O3
- Emissions
- Modelling
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Dive into the research topics of 'Microkinetic modelling for selective catalytic reduction (SCR) of NOx by propane in a silver-based automotive catalytic converter'. Together they form a unique fingerprint.Projects
- 1 Finished
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novel Compact After Treatment Systems for Simultaneous Reduction of Diesel Engine NOx, PM,CO and HC Emissions
Tsolakis, A. (Principal Investigator), Harrison, R. (Co-Investigator) & Wyszynski, M. (Co-Investigator)
Engineering & Physical Science Research Council
4/01/10 → 31/05/13
Project: Research Councils