Metal-Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

Hatem M. Titi; Mihails Arhangelskis; Athanassios D. Katsenis; Cristina Mottillo; Ghada Ayoub; Jean Louis Do; Athena M. Fidelli; Robin D. Rogers; Tomislav Friščić

doi:10.1021/acs.chemmater.9b01488

Metal-Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

Hatem M. Titi
, Mihails Arhangelskis
, Athanassios D. Katsenis
, Cristina Mottillo
, Ghada Ayoub
, Jean Louis Do
, Athena M. Fidelli
, Robin D. Rogers^*
, Tomislav Friščić

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Systematic investigation of combustion energies for popular metal-organic framework materials reveals energy content comparable to conventional energetic materials, which can be further modified and fine-tuned through the control of framework topology or isostructural ligand replacement to yield energy densities comparable to conventional energetic materials such as trinitrotoluene and hydrazine-, diesel-, or kerosene-based fuels.

Original language	English
Pages (from-to)	4882-4888
Number of pages	7
Journal	Chemistry of Materials
Volume	31
Issue number	13
DOIs	https://doi.org/10.1021/acs.chemmater.9b01488
Publication status	Published - 3 Jun 2019

Bibliographical note

Publisher Copyright:
© 2019 American Chemical Society.

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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10.1021/acs.chemmater.9b01488

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title = "Metal-Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs",

abstract = "Systematic investigation of combustion energies for popular metal-organic framework materials reveals energy content comparable to conventional energetic materials, which can be further modified and fine-tuned through the control of framework topology or isostructural ligand replacement to yield energy densities comparable to conventional energetic materials such as trinitrotoluene and hydrazine-, diesel-, or kerosene-based fuels.",

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year = "2019",

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doi = "10.1021/acs.chemmater.9b01488",

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AU - Titi, Hatem M.

AU - Arhangelskis, Mihails

AU - Katsenis, Athanassios D.

AU - Mottillo, Cristina

AU - Ayoub, Ghada

AU - Do, Jean Louis

AU - Fidelli, Athena M.

AU - Rogers, Robin D.

AU - Friščić, Tomislav

PY - 2019/6/3

Y1 - 2019/6/3

N2 - Systematic investigation of combustion energies for popular metal-organic framework materials reveals energy content comparable to conventional energetic materials, which can be further modified and fine-tuned through the control of framework topology or isostructural ligand replacement to yield energy densities comparable to conventional energetic materials such as trinitrotoluene and hydrazine-, diesel-, or kerosene-based fuels.

AB - Systematic investigation of combustion energies for popular metal-organic framework materials reveals energy content comparable to conventional energetic materials, which can be further modified and fine-tuned through the control of framework topology or isostructural ligand replacement to yield energy densities comparable to conventional energetic materials such as trinitrotoluene and hydrazine-, diesel-, or kerosene-based fuels.

UR - https://www.scopus.com/pages/publications/85070559297

U2 - 10.1021/acs.chemmater.9b01488

DO - 10.1021/acs.chemmater.9b01488

M3 - Article

AN - SCOPUS:85070559297

SN - 0897-4756

VL - 31

SP - 4882

EP - 4888

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 13

ER -

Metal-Organic Frameworks as Fuels for Advanced Applications: Evaluating and Modifying the Combustion Energy of Popular MOFs

Abstract

Bibliographical note

ASJC Scopus subject areas

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